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प्रश्न
Account for the following:
N-ethylethanamine boils at 329.3 K and butanamine boils at 350.8 K, although both are isomeric in nature.
उत्तर
Primary and secondary amines are engaged in intermolecular association due to hydrogen bonding between nitrogen of one and hydrogen of another molecule. Due to the presence of three hydrogen atoms, the intermolecular association is more in primary amines than in secondary amines as there are two hydrogen atoms available for hydrogen bond formation in it.
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संबंधित प्रश्न
Identify the weakest base amongst the following :
(a) p- methoxyaniline
(b) o-toluidine
(c) benzene - 1, 4 - diamine
(d) 4 - aminobenzoic acid
Give reason for the following:
Primary amines have higher boiling point than tertiary amines.
How will you convert Benzene into N, N-dimethylaniline?
Give reason (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
Answer in one sentence.
Arrange the following amines in increasing order of boiling points.
n-propylamine, ethylmethyl amine, trimethylamine.
The CORRECT decreasing order of boiling points is:
Which of the following should be most volatile?
A compound Z with molecular formula \[\ce{C3H9N}\] reacts with \[\ce{C6H5SO2Cl}\] to give a solid, insoluble in alkali. Identify Z.
Dimerisation of carboxylic acids is due to
Arrange the decreasing boiling point.
\[\ce{CH3COOH, C2H5OH, CH3NH2, CH3OCH3}\]
