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Complete the Following Statement by Selecting the Correct Alternative from the Choices Given: for a Spontaneous Reaction δG° and E° Cell Will Be Respectively: - Chemistry (Theory)

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प्रश्न

Complete the following statement by selecting the correct alternative from the choices given:  

For a spontaneous reaction ΔG° and E° cell will be respectively:

विकल्प

  • -ve and +ve

  • +ve and -ve

  • +ve and +ve

  • -ve and -ve

MCQ

उत्तर

-ve and +ve

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2016-2017 (March)

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संबंधित प्रश्न

Calculate the e.m.f. of the following cell at 298 K:

Fe(s) | Fe2+ (0.001 M) | | H+ (0.01 M) | H2(g) (1 bar) | Pt(s)

Given that \[\ce{E^0_{cell}}\] = 0.44 V

[log 2 = 0.3010, log 3 = 0.4771, log 10 = 1]


Calculate emf of the following cell at 298 K:
Mg(s) | Mg2+(0.1 M) || Cu2+ (0.01) | Cu(s)
[Given Eocell = +2.71 V, 1 F = 96500 C mol–1]


Calculate the value of Ecell at 298 K for the following cell:

`(Al)/(Al^(3+)) (0.01M) || Sn^(2+) ((0.015 M))/(Sn)`

`E°  _(Al^(3+))/(AI)= -1.66 " Volt and " E° _(Sn^(2+)) /(Sn) = -0.14` volt


For a general electrochemical reaction of the type:

\[\ce{{a}A + {b}B ⇔ {c}C + {d}D}\]

Nernst equation can be written as:


Calculate ΔrG0 and log Kc for the following cell:

\[\ce{Ni(s) + 2Ag^+(aq) -> Ni^{2+}(aq) + 2Ag(s)}\]

Given that \[\ce{E^0_{cell}}\] = 1.05 V, 1F = 96,500 C mol–1.


Calculate the emf of the following cell at 298 K:

Fe(s) | Fe2+ (0.01 M) | | H+ (1 M) | H2(g) (1 bar) Pt(s)

Given \[\ce{E^0_{cell}}\] = 0.44 V.


Calculate the value of \[\ce{E^\circ}\]cell, E cell and ΔG that can be obtained from the following cell at 298 K.

\[\ce{Al/Al^3+ _{(0.01 M)} // Sn^{2+} _{(0.015 M)}/Sn}\]

Given: \[\ce{E^\circ  Al^3+/Al = -1.66 V; E^\circ\phantom{.}Sn^2+/Sn = -0.14 V}\]


Write the Nernst equation and emf of the following cell at 298 K:

\[\ce{Fe_{(s)} | Fe^{2+} (0.001 M) || H^+ (1 M) | H2_{(g)} (1 bar) | Pt_{(s)}}\]


Write the Nernst equation and emf of the following cell at 298 K:

\[\ce{Sn_{(s)} | Sn^{2+} (0.050 M) || H^+ (0.020 M) | H2_{(g)} (1 bar) | Pt_{(s)}}\]


Write the Nernst equation and emf of the following cell at 298 K:

\[\ce{Pt_{(s)} | Br^- (0.010 M) | Br2_{(l)} || H^+ (0.030 M) | H2_{(g)} (1 bar) | Pt_{(s)}}\]


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