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प्रश्न
Do the electrodes in an electrolytic cell have fixed polarity like a battery?
उत्तर
No, the electrodes in an electrolytic cell do not have fixed polarity like that of a battery. If we take an electrolytic cell consisting of the Ag electrodes and the AgNO3 as electrolyte. When the battery is connected to it, the end to which the positive terminal of the battery is connected is the anode and the end to which the negative terminal is connected is the cathode.
\[{NO}_3^-\] ions are deposited at the anode and Ag+ ions are deposited at the cathode. When the connection of the electrolytic cell is reversed, the polarities of the electrodes are also reversed.
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संबंधित प्रश्न
Distinguish between emf and terminal voltage of a cell.
A cell of emf 'E' and internal resistance 'r' is connected across a variable load resistor R. Draw the plots of the terminal voltage V versus (i) R and (ii) the current I.
It is found that when R = 4 Ω, the current is 1 A and when R is increased to 9 Ω, the current reduces to 0.5 A. Find the values of the emf E and internal resistance r.
The earth’s surface has a negative surface charge density of 10−9 C m−2. The potential difference of 400 kV between the top of the atmosphere and the surface results (due to the low conductivity of the lower atmosphere) in a current of only 1800 A over the entire globe. If there were no mechanism of sustaining atmospheric electric field, how much time (roughly) would be required to neutralise the earth’s surface? (This never happens in practice because there is a mechanism to replenish electric charges, namely the continual thunderstorms and lightning in different parts of the globe). (Radius of earth = 6.37 × 106 m.)
A secondary cell after long use has an emf of 1.9 V and a large internal resistance of 380 Ω. What maximum current can be drawn from the cell? Could the cell drive the starting motor of a car?
A long straight current carrying wire passes normally through the centre of circular loop. If the current through the wire increases, will there be an induced emf in the loop? Justify.
Plot a graph showing variation of voltage vs the current drawn from the cell. How can one get information from this plot about the emf of the cell and its internal resistance?
A cell of emf E and internal resistance r is connected to two external resistance R1 and R2 and a perfect ammeter. The current in the circuit is measured in four different situations:
(i) without any external resistance in the circuit
(ii) with resistance R1 only
(iii) with R1 and R2 in series combination
(iv) with R1 and R2 in parallel combination
The currents measured in the four cases are 0.42 A, 1.05 A, 1.4 A and 4.2 A, but not necessarily in the order. Identify the currents corresponding to the four cases mentioned above.
Two non-ideal batteries are connected in series. Consider the following statements:-
(A) The equivalent emf is larger than either of the two emfs.
(B) The equivalent internal resistance is smaller than either of the two internal resistances.
Two non-ideal batteries are connected in parallel. Consider the following statements:-
(A) The equivalent emf is smaller than either of the two emfs.
(B) The equivalent internal resistance is smaller than either of the two internal resistances.
A battery of emf 100 V and a resistor of resistance 10 kΩ are joined in series. This system is used as a source to supply current to an external resistance R. If R is not greater than 100 Ω, the current through it is constant up to two significant digits.
Find its value. This is the basic principle of a constant-current source.
Apply the first law of thermodynamics to a resistor carrying a current i. Identify which of the quantities ∆Q, ∆U and ∆W are zero, positive and negative.
Do all thermocouples have a neutral temperature?
The temperatures of the junctions of a bismuth-silver thermocouple are maintained at 0°C and 0.001°C. Find the thermo-emf (Seebeck emf) developed. For bismuth-silver, a = − 46 × 10−6 V°C−1 and b = −0.48 × 10−6 V°C−2.
A plate of area 10 cm2 is to be electroplated with copper (density 9000 kg m−3) to a thickness of 10 micrometres on both sides, using a cell of 12 V. Calculate the energy spent by the cell in the process of deposition. If this energy is used to heat 100 g of water, calculate the rise in the temperature of the water. ECE of copper = 3 × 10−7 kg C−1and specific heat capacity of water = 4200 J kg−1.
A cell having an emf E and internal resistance r is connected across a variable external resistance R. As the resistance R is increased, the plot of potential difference V across R is given by ______.
If n cells each of emf e and internal resistance r are connected in parallel, then the total emf and internal resistance will be ______.
A straight line plot showing the terminal potential difference (V) of a cell as a function of current (I) drawn from it, is shown in the figure. The internal resistance of the cell would be then ______.
A block of metal is heated directly by dissipating power in the internal resistance of block. Because of temperature rise, the resistance increases exponentially with time and is given by R(t) = 0.5 e2t, where t is in second. The block is connected across a 110 V source and dissipates 7644 J heat energy over a certain period of time. This period of time is ______ × 10-1 sec (take ln 0.367 = -1).
