Advertisements
Advertisements
प्रश्न
A face centred cube (FCC) consists of how many atoms? Explain
उत्तर
Face-centred cubic lattice (fcc):
1) In face-centred cubic unit cell, eight constituent particles (spheres) are present at eight corners of unit cell. Six constituent particles (spheres) are present at centres of six faces
2) A constituent particle present at a corner is shared by eight neighbouring unit cells. Its contribution to a unit cell is only 1/8. Thus, the number of atoms present at corners per unit cell
= 8 corner atoms x 1/8 atom per unit cell = 1
3) A constituent particle present at the centre of a face is shared by two neighbouring unit cells. Its contribution to a unit cell is only 1/2.
The number of atoms present at faces per unit cell
= 6 atoms at the faces x 1/2 atom per unit cell = 3
4) The total number of atoms per unit cell = 1 + 3 = 4
Thus, a face-centred cubic unit cell has 4 atoms per unit cell.
APPEARS IN
संबंधित प्रश्न
How many atoms constitute one unit cell of a face-centered cubic crystal?
Gold occurs as face centred cube and has a density of 19.30 kg dm-3. Calculate atomic radius of gold (Molar mass of Au = 197)
Face centred cubic crystal lattice of copper has density of 8.966 g.cm-3. Calculate the volume of the unit cell. Given molar mass of copper is 63.5 g mol-1 and Avogadro number NA is 6.022 x 1023 mol-1
An element crystallises in a b.c.c lattice with cell edge of 500 pm. The density of the element is 7.5g cm-3. How many atoms are present in 300 g of the element?
An element with molar mass 27 g mol−1 forms a cubic unit cell with edge length 4.05 ✕ 10−8 cm. If its density is 2.7 g cm−3, what is the nature of the cubic unit cell?
Distinguish between Hexagonal and monoclinic unit cells
Distinguish between Face-centred and end-centred unit cells.
An element with molar mass 2.7 × 10-2 kg mol-1 forms a cubic unit cell with edge length 405 pm. If its density is 2.7 × 103 kg m−3, what is the nature of the cubic unit cell?
What is the coordination number of atoms:
(a) in a cubic close-packed structure?
(b) in a body-centred cubic structure?
How can you determine the atomic mass of an unknown metal if you know its density and the dimension of its unit cell? Explain.
Explain with reason sign conventions of ΔS in the following reaction
N2(g) + 3H2(g) → 2NH3(g)
Explain with reason sign conventions of ΔS in the following reaction
CO2(g) → CO2(g)
Calculate the number of unit cells in 8.1 g of aluminium if it crystallizes in a f.c.c. structure. (Atomic mass of Al = 27 g mol–1)
The density of silver having an atomic mass of 107.8 g mol- 1 is 10.8 g cm-3. If the edge length of cubic unit cell is 4.05 × 10- 8
cm, find the number of silver atoms in the unit cell.
( NA = 6.022 × 1023, 1 Å = 10-8 cm)
Number of types of orthorhombic unit cell is ___________.
What is the total number of atoms per unit cell in a face-centered cubic structure?
The number of atoms per unit cell in a body centered cubic structure is ____________.
The empty space in the body-centered cubic lattice is ____________.
The number of atoms contained in a fcc unit cell of a monoatomic substance is ____________.
The edge length of fcc cell is 508 pm. If the radius of cation is 110 pm, the radius of anion is:
The density of a metal which crystallises in bcc lattice with unit cell edge length 300 pm and molar mass 50 g mol−1 will be:
The percentage of empty space in a body centred cubic arrangement is ______.
Match the type of unit cell given in Column I with the features given in Column II.
Column I | Column II |
(i) Primitive cubic unit cell | (a) Each of the three perpendicular edges compulsorily have the different edge length i.e; a ≠ b ≠ c. |
(ii) Body centred cubic unit cell | (b) Number of atoms per unit cell is one. |
(iii) Face centred cubic unit cell | (c) Each of the three perpendicular edges compulsorily have the same edge length i.e; a = b = c. |
(iv) End centred orthorhombic cell | (d) In addition to the contribution from unit cell the corner atoms the number of atoms present in a unit cell is one. |
(e) In addition to the contribution from the corner atoms the number of atoms present in a unit cell is three. |
The coordination number for body center cubic (BCC) system is
An element A (Atomic weight = 100) having bcc structure has a unit cell edge length 400 pm. The number of atoms in 10 g of A is ______ × 1022 unit cells.