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प्रश्न
Give evidence that [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl are ionization isomers.
उत्तर
Ionization isomers dissolve in water to give different ions, hence giving different reactions with different reagents.
\[\ce{[Co(NH3)5Cl]SO4 + Ba^{2+} -> BaSO4_{(s)}}\]
\[\ce{[Co(NH3)5SO4]Cl + Ba^{2+} -> {No Reaction}}\]
\[\ce{[Co(NH3)5Cl]SO4 + Ag^+ -> {No Reaction}}\]
\[\ce{[Co(NH3)5SO4]Cl + Ag^+ -> AgCl_{(s)}}\]
Since the given complexes give different reactions with different reagents, hence they are ionization isomers.
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संबंधित प्रश्न
The complex ion `[Co(H_2O)_5 (ONO)]^(2+) `
(A) linkage isomer
(B) ionisation isomer
(C) co-ordination isomer
(D) geometrical isomer
What type of isomerism is shown by the complex [Co(en)3]Cl3
What type of isomerism is shown by the complex [Co(NH3)6] [Cr(CN)6]?
What type of isomerism is shown by the complex [Co(NH3)5(SCN)]2+?
What type of isomerism is exhibited by the complex `[Co(NH_3)_5Cl]SO_4`?
Write the IUPAC name of the complex [Cr(NH3)4Cl2]+. What type of isomerism does it exhibit?
Write IUPAC name of the complex [Pt(en)2Cl2]. Draw structures of geometrical isomers for this complex.
Which of the following isomer has the highest melting point?
Due to the presence of ambidentate ligands coordination compounds show isomerism. Palladium complexes of the type \[\ce{Pd(C6H5)2 (SCN)2]}\] and \[\ce{[Pd(C6H5)2 (NCS)2]}\] are ______.
The compounds \[\ce{[CO(SO4)(NH3)5]Br}\] and \[\ce{[Co(SO4)(NH3)5]Cl}\] represent
Match the complex species given in Column I with the possible isomerism given in Column II and assign the correct code:
| Column I (Complex species) | Column II (Isomerism) |
| A. \[\ce{[Co(NH3)4 Cl2]^+}\] | 1. optical |
| B. \[\ce{cis-[Co(en)2 Cl2]^+}\] | 2. ionisation |
| C. \[\ce{[Co(NH3)5 (NO2)]Cl2}\] | 3. coordination |
| D. \[\ce{[Co(NH3)6][Cr(CN)6]}\] | 4. geometrical |
| 5. linkage |
Assertion: Linkage isomerism arises in coordination compounds containing ambidentate ligand.
Reason: Ambidentate ligand has two different donor atoms
A functional isomer of 1-butyne is
The diamagnetic species is:-
Which of the following compounds exhibits linkage isomerism?
Which isomer of C5H10 gives a single monochloro compound C5H9Cl in bright sunlight?
The complex [Co(NH3)5(NO2)]Cl2 is red in colour. Give IUPAC the name of its linkage isomer.
Indicate the types of isomerism exhibited by the following complexes and draw the structures for this isomer:
Pt(NH3)(H2O)Cl2
