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प्रश्न
The compounds \[\ce{[CO(SO4)(NH3)5]Br}\] and \[\ce{[Co(SO4)(NH3)5]Cl}\] represent
विकल्प
linkage isomerism
ionisation isomerism
coordination isomerism
no isomerism
उत्तर
no isomerism
Explanation:
\[\ce{[Co(SO4)(NH3)5]Br}\] and \[\ce{[CO(SO4)(NH3)5]Cl}\] represent no isomerism because they are different compounds.
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संबंधित प्रश्न
What type of isomerism is shown by the complex [Co(NH3)6] [Cr(CN)6]?
What type of isomerism is shown by the complex [Co(NH3)5(SCN)]2+?
What type of isomerism is exhibited by the complex `[Co(NH_3)_5Cl]SO_4`?
Which of the following isomer has the highest melting point?
Due to the presence of ambidentate ligands coordination compounds show isomerism. Palladium complexes of the type \[\ce{Pd(C6H5)2 (SCN)2]}\] and \[\ce{[Pd(C6H5)2 (NCS)2]}\] are ______.
Match the complex species given in Column I with the possible isomerism given in Column II and assign the correct code:
| Column I (Complex species) | Column II (Isomerism) |
| A. \[\ce{[Co(NH3)4 Cl2]^+}\] | 1. optical |
| B. \[\ce{cis-[Co(en)2 Cl2]^+}\] | 2. ionisation |
| C. \[\ce{[Co(NH3)5 (NO2)]Cl2}\] | 3. coordination |
| D. \[\ce{[Co(NH3)6][Cr(CN)6]}\] | 4. geometrical |
| 5. linkage |
Assertion: Linkage isomerism arises in coordination compounds containing ambidentate ligand.
Reason: Ambidentate ligand has two different donor atoms
CoSO4Cl.5NH3 exists in two isomeric forms ‘A’ and ‘B’. Isomer ‘A’ reacts with AgNO3 to give white precipitate, but does not react with BaCl2. Isomer ‘B’ gives white precipitate with BaCl2 but does not react with AgNO3. Answer the following questions.
- Identify ‘A’ and ‘B’ and write their structural formulas.
- Name the type of isomerism involved.
- Give the IUPAC name of ‘A’ and ‘B’.
Which of the following compounds exhibits linkage isomerism?
Indicate the types of isomerism exhibited by the following complexes and draw the structures for this isomer:
Pt(NH3)(H2O)Cl2
