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प्रश्न
The compounds \[\ce{[CO(SO4)(NH3)5]Br}\] and \[\ce{[Co(SO4)(NH3)5]Cl}\] represent
पर्याय
linkage isomerism
ionisation isomerism
coordination isomerism
no isomerism
उत्तर
no isomerism
Explanation:
\[\ce{[Co(SO4)(NH3)5]Br}\] and \[\ce{[CO(SO4)(NH3)5]Cl}\] represent no isomerism because they are different compounds.
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संबंधित प्रश्न
The complex ion `[Co(H_2O)_5 (ONO)]^(2+) `
(A) linkage isomer
(B) ionisation isomer
(C) co-ordination isomer
(D) geometrical isomer
What type of isomerism is shown by the complex [Co(NH3)6] [Cr(CN)6]?
What type of isomerism is exhibited by the complex `[Co(NH_3)_5Cl]SO_4`?
Which of the following pair contains a complex salt and double salt respectively?
What kind of isomerism exists between \[\ce{[Cr(H2O)6]Cl3}\] (violet) and \[\ce{[Cr(H2O)5Cl]Cl2 . H2O}\] (greyish-green)?
Name the type of isomerism when ambidentate ligands are attached to central metal ion. Give two examples of ambidentate ligands.
Match the complex species given in Column I with the possible isomerism given in Column II and assign the correct code:
| Column I (Complex species) | Column II (Isomerism) |
| A. \[\ce{[Co(NH3)4 Cl2]^+}\] | 1. optical |
| B. \[\ce{cis-[Co(en)2 Cl2]^+}\] | 2. ionisation |
| C. \[\ce{[Co(NH3)5 (NO2)]Cl2}\] | 3. coordination |
| D. \[\ce{[Co(NH3)6][Cr(CN)6]}\] | 4. geometrical |
| 5. linkage |
CoSO4Cl.5NH3 exists in two isomeric forms ‘A’ and ‘B’. Isomer ‘A’ reacts with AgNO3 to give white precipitate, but does not react with BaCl2. Isomer ‘B’ gives white precipitate with BaCl2 but does not react with AgNO3. Answer the following questions.
- Identify ‘A’ and ‘B’ and write their structural formulas.
- Name the type of isomerism involved.
- Give the IUPAC name of ‘A’ and ‘B’.
The complex [Co(NH3)5(NO2)]Cl2 is red in colour. Give IUPAC the name of its linkage isomer.
Indicate the types of isomerism exhibited by the following complexes and draw the structures for this isomer:
Pt(NH3)(H2O)Cl2
