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State Kohlrausch law of independent migration of ions. - Chemistry

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प्रश्न

State Kohlrausch law of independent migration of ions.

लघु उत्तरीय

उत्तर

Kohlrausch law states that “at infinite dilution each ion migrates independent of co-ion and contributes to total molar conductivity of an electrolyte irrespective of the nature of other ion to which it is associated.”

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Electrical Conductance of Solution
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अध्याय 5: Electrochemistry - Short answer questions (Type- II)

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एससीईआरटी महाराष्ट्र Chemistry [English] 12 Standard HSC
अध्याय 5 Electrochemistry
Short answer questions (Type- II) | Q 1.1

संबंधित प्रश्न

0.05 M NaOH solution offered a resistance of 31.6 Ω in a conductivity cell at 298 K. If the cell constant of the cell is 0.367 cm-1, calculate the molar conductivity of NaOH solution.


The molar conductivity of 0.05 M BaCl2 solution at 25° C is 223Ω-1 cm2 mol-1. What is its conductivity?


Choose the most correct option.

Two solutions have the ratio of their concentrations 0.4 and ratio of their conductivities 0.216. The ratio of their molar conductivities will be ______.


Answer the following in brief.

Explain the effect of dilution of the solution on conductivity.


Answer the following:

What is Kohlrausch law of independent migration of ions? How is it useful in obtaining molar conductivity at zero concentration of a weak electrolyte? Explain with an example.


SI unit of conductivity is _______.


Write three important steps required to determine molar conductivity.


Molar conductance of BaCl2, H2SO4 and HCl at infinite dilution are X1, X2 and X3 respectively. Molar conductance of BaSO4 at infinite dilution is ____________.


The CORRECT unit of molar conductivity is ____________.


The conductivity of 0.02 M solution of NaCl is 2.6 × 10−2 S cm−1. What is its molar conductivity?


Which among the following solution has the highest conductivity (k) value?


The molar conductivities at zero concentration for Ca2+ and CaCl2 are 104 and 256.8 Ω−1 cm2 mol−1 respectively. The molar conductivity at zero concentration for Cl is ____________.


The SI unit of resistivity and molar conductivity are respectively ____________.


In 2 hours, a certain current liberates 0.504 g hydrogen. How many grams of copper can be deposited by the same current flowing for the same time in a CuSO4 solution?

(Molar mass of Cu = 63.5 g mol−1, H2 = 2.0 g mol−1)


What is the relation between cell constant, conductivity and electrical resistance?


What is the value of cell constant if conductance and conductivity of a solution is same?


What will be the concentration of NaCl solution, if the molar conductivity and conductivity of NaCl solution is 124.3 Ω-1 cm2 mol-1 and 1.243 × 10-4 Ω-1 cmrespectively?


A conductivity cell dipped in 0.5 M KCl gives a resistance of 250 ohms. If the conductivity of KC I solution is 6.68 × 10-3 S cm-1, what is the cell constant?


If the resistivity of 0.1 M KCI solution is 50 Ω cm, what is it's molar conductivity?


Specific conductance of 0.1 M sodium chloride solution is 1.06 × 10−2 ohm−1 cm−1. Its molar conductance in ohm−1 cm2 mol−1 is ______.


Molar conductivities at infinite dilution of Mg2+ and Br- are 105.8 Ω-1 cm2 mol-1 and 78.2 Ω-1 cm2 mol-1 respectively. Calculate molar conductivity at zero concentration of MgBr2.


Define cell constant. Give its units.


Write the relation between molar conductivity and molar ionic conductivities for the electrolytes:

  1. Na2SO4
  2. AlCl3

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