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प्रश्न
The equilibrium constant for the reaction:
`N_(2(g)) + 3H_(2(g)) ⇌ 2NH_(3(g)) at 715 K, is 6.0 xx 10^(-2)`
If, in a particular reaction, there ate 0·25 mol L-1 of H2. and 0·06 mol L-1 of NH3 present, calculate the concentration of N2 at equilibrium
उत्तर
`N_(2(g)) + 3H_(2(g)) ⇌ 2NH_(3(g))`
K (equilibrium constant) = `6.0 xx 10^(-2) mol L^(-1)`
Temperature (T) = 715 K
`[H_2] = 0.25 mol L^(-1)`
`[NH_3] = 0.06 mol L^(-1)`
`[N_2] = ?`
`K= [NH_3]^2/([N_2]xx[H_2]^3)`
`[N_2] = [NH_3]^2/[Kxx[H_2]^3]`
`= (0.06)^2/(6.0 xx 10^(-2) xx (0.25)^3)`
`= 0.0036/(6.0 xx 10^(-2)xx 0.015625)`
`[N_2] = 3.84 mol L^(-1)`
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Reversible Reactions and Dynamic Equilibrium - Equilibrium Constant in Terms of Partial Pressures Kp
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