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The Equilibrium Constant for the Reaction: `N_(2(G)) + 3h_(2(G)) ⇌ 2nh_(3(G)) at 715 K, is 6.0 Xx 10^(-2)` If, in a Particular Reaction, There Ate 0·25 Mol L-1 of H2. and 0·06 Mol L-1 of Nh3 Present, Calculate the Concentration of N2 at Equilibrium - Chemistry (Theory)

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Question

The equilibrium constant for the reaction: 

`N_(2(g)) + 3H_(2(g)) ⇌ 2NH_(3(g)) at 715 K, is 6.0 xx 10^(-2)`

If, in a particular reaction, there ate 0·25 mol L-1 of H2. and 0·06 mol L-1 of NH3 present, calculate the concentration of N2 at equilibrium

Solution

`N_(2(g)) + 3H_(2(g)) ⇌ 2NH_(3(g))`

K (equilibrium constant) = `6.0 xx 10^(-2) mol L^(-1)`

Temperature (T) = 715 K

`[H_2] = 0.25 mol L^(-1)`

`[NH_3] = 0.06 mol L^(-1)`

`[N_2] = ?`

`K= [NH_3]^2/([N_2]xx[H_2]^3)`

`[N_2] = [NH_3]^2/[Kxx[H_2]^3]`

`= (0.06)^2/(6.0 xx 10^(-2) xx (0.25)^3)`

`= 0.0036/(6.0 xx 10^(-2)xx 0.015625)`

`[N_2] = 3.84  mol L^(-1)`

shaalaa.com
Reversible Reactions and Dynamic Equilibrium - Equilibrium Constant in Terms of Partial Pressures Kp
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2014-2015 (March)

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