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प्रश्न
What is lanthanoid contraction? Write the.............
उत्तर
The regular decrease in atomic and ionic radii from lanthanum to lutetium with increasing atomic number is called lanthanoid contraction.
Consequences :
The net result of the lanthanoid contraction is that the second and third d-series exhibit similar radii
Zr =160 pm
and Hf = 159pm
They have very similar physical and chemical properties.
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संबंधित प्रश्न
Compare the chemistry of actinoids with that of the lanthanoids with special reference to oxidation state.
Write the different oxidation states of iron
What is lanthanoid contraction?
What is Lanthanoid contraction?
What is Lanthanoid contraction?
Match the compounds/elements given in Column I with uses given in Column II.
Column I (Compound/element) | Column II (Use) | |
(i) | Lanthanoid oxide | (a) Production of iron alloy |
(ii) | Lanthanoid | (b) Television screen |
(iii) | Misch metal | (c) Petroleum cracking |
(iv) | Magnesium based alloy is constituent of | (d) Lanthanoid metal + iron |
(v) | Mixed oxides of lanthanoids are employed | (e) Bullets |
(f) In X-ray screen |
Match the property given in Column I with the element given in Column II.
Column I (Property) | Column II (Element) | |
(i) | Lanthanoid which shows +4 oxidation state |
(a) Pm |
(ii) | Lanthanoid which can show +2 oxidation state |
(b) Ce |
(iii) | Radioactive lanthanoid | (c) Lu |
(iv) | Lanthanoid which has 4f7 electronic configuration in +3 oxidation state |
(d) Eu |
(v) | Lanthanoid which has 4f14 electronic configuration in +3 oxidation state |
(e) Gd |
(f) Dy |
On the basis of Lanthanoid contraction, explain the following:
Radii of 4d and 5d block elements.
Write a note on lanthanoids.
Why is Mn2+ ion more stable than Fe2+ ion?
(Atomic numbers of Mn = 25 and Fe = 26)