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Write down the IUPAC name of the following complex and indicate the oxidation state, electronic configuration and coordination number. [CrCl3(py)3] - Chemistry

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प्रश्न

Write down the IUPAC name of the following complex and indicate the oxidation state, electronic configuration and coordination number. Also, give the stereochemistry and magnetic moment of the complex:

[CrCl3(py)3]

संक्षेप में उत्तर

उत्तर

IUPAC name of the hybrid compound Oxidation state of the central metal Coordination number Shape Central metal ion Electronic configuration The value of n and the magnetic moment
Trichloridotripyridinechromium(III) x + 5 × (0) + 3 × (−1) = 0
∴ x = +3
6 Octahedral Co3+ d3, \[\ce{t^3_{2g}}\]

`sqrt(3(3 + 2))`
= `sqrt15`
∼ 4BM

Stereochemistry:

Both isomers are optically active. Therefore, a total of 4 isomers exist.

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अध्याय 9: Coordinate Compounds - Exercises [पृष्ठ २५९]

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एनसीईआरटी Chemistry [English] Class 12
अध्याय 9 Coordinate Compounds
Exercises | Q 24.3 | पृष्ठ २५९
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