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ISC (Science) ISC Class 12 - CISCE Question Bank Solutions for Chemistry (Theory)

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Chemistry (Theory)
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Match the following:

1 Disaccharide a Lucas reagent
2 Carbylamine b Condensation polymer
3 Dacron c Obnoxious smell
4 Low spin complex `d^2sp^3` d Sucrose
5 Anhydrous `ZnCl_2 + conc.HCl` e Hexaamminecobalt(III)ion

 

[0.15] Cyanides, Isocyanides, Nitro compounds, Amines and Diazonium Salt
Chapter: [0.15] Cyanides, Isocyanides, Nitro compounds, Amines and Diazonium Salt
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Name the important ore of silver. Write all the steps and reactions involved in the Cyanide process for the extraction of silver from its ore.

[0.15] Cyanides, Isocyanides, Nitro compounds, Amines and Diazonium Salt
Chapter: [0.15] Cyanides, Isocyanides, Nitro compounds, Amines and Diazonium Salt
Concept: undefined > undefined

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Answer the followiiig questions: 
Identify the compounds A, B, C and D in the given reaction:

[0.131] Carbonyl compounds
Chapter: [0.131] Carbonyl compounds
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Identify the compounds A, B, C, D, E and F:  

[0.131] Carbonyl compounds
Chapter: [0.131] Carbonyl compounds
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For the complexion of [Co(NH3)6]3+
(i) State the hybridisation of the complex.
(ii) State the magnetic nature of the complex.

[0.07] Coordination Compounds
Chapter: [0.07] Coordination Compounds
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 Give a reason for the following:

Fluorine gives only one oxide but chlorine gives a series of oxides.

[0.08] Chemistry of p-Block Elements: Group 16, 17, 18
Chapter: [0.08] Chemistry of p-Block Elements: Group 16, 17, 18
Concept: undefined > undefined

Write the structures of all enantiomers possible for lactic acid.

[0.17] Biomolecules – carbohydrates, proteins, enzymes, vitamins and nucleic acids
Chapter: [0.17] Biomolecules – carbohydrates, proteins, enzymes, vitamins and nucleic acids
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Give balanced equations for the following reactions: 

(i) Acetaldehyde is heated with hydroiodic acid in the presence of red phosphorous.
(ii) Calcium acetate is subjected to dry distillation.
(iii) Sodium ethoxide is treated with ethyl bromide.
(iv) Benzaldehyde is treated with sodium bisulphite.

[0.131] Carbonyl compounds
Chapter: [0.131] Carbonyl compounds
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Give balanced chemical equations for the following reactions:

(1) Acetaldehyde reacts with hydrogen cyanide.
(2) Acetone reacts with phenylhydrazine.
(3) Acetic acid is treated with ethanol and a drop of conc. H2SO4.

[0.131] Carbonyl compounds
Chapter: [0.131] Carbonyl compounds
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Give one chemical test each to distinguish between the following pairs of compounds:
(1) Acetone and benzaldehyde.
(2) Phenol and benzoic acid.

[0.131] Carbonyl compounds
Chapter: [0.131] Carbonyl compounds
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Choose the most correct option.

Which one of the following has the lowest acidity?

[0.131] Carbonyl compounds
Chapter: [0.131] Carbonyl compounds
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Identify the compounds [A], [B] and [C] in the following reaction.

\[\ce{C6H5NO2->[6{[H]}][Sn/HCl][A]->[HNO2 + HCl][273K-278K][B]->[C6H5NH2] [C]}\]

[0.15] Cyanides, Isocyanides, Nitro compounds, Amines and Diazonium Salt
Chapter: [0.15] Cyanides, Isocyanides, Nitro compounds, Amines and Diazonium Salt
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Identify the compounds [A], [B] and [C] in the following reaction.

\[\ce{CH3CH2NH2->[(1) HNO2][(2) P/Cl2][A]->[(1) KCN][(2) H2O/H+][B]->[(1) NH3/heat][(2) Br2/KOH][C]}\]

[0.15] Cyanides, Isocyanides, Nitro compounds, Amines and Diazonium Salt
Chapter: [0.15] Cyanides, Isocyanides, Nitro compounds, Amines and Diazonium Salt
Concept: undefined > undefined

In non-ideal solution, what type of deviation shows the formation of maximum boiling azeotropes?

[0.011000000000000001] Raoult's law and colligative properties
Chapter: [0.011000000000000001] Raoult's law and colligative properties
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Define electrochemical cell

[0.062] Galvanic cells, mechanism of current production in a galvanic cell;
Chapter: [0.062] Galvanic cells, mechanism of current production in a galvanic cell;
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State Raoult’s law for the solution containing volatile components

[0.011000000000000001] Raoult's law and colligative properties
Chapter: [0.011000000000000001] Raoult's law and colligative properties
Concept: undefined > undefined

Why does the cell potential of mercury cell remain constant throughout its life?

[0.062] Galvanic cells, mechanism of current production in a galvanic cell;
Chapter: [0.062] Galvanic cells, mechanism of current production in a galvanic cell;
Concept: undefined > undefined

From the given cells:

Lead storage cell, Mercury cell, Fuel cell and Dry cell

Answer the following:

(i) Which cell is used in hearing aids?

(ii) Which cell was used in Apollo Space Programme?

(iii) Which cell is used in automobiles and inverters?

(iv) Which cell does not have long life?

[0.062] Galvanic cells, mechanism of current production in a galvanic cell;
Chapter: [0.062] Galvanic cells, mechanism of current production in a galvanic cell;
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What is meant by positive deviations from Raoult's law? Give an example. What is the sign of ∆mixH for positive deviation?

[0.011000000000000001] Raoult's law and colligative properties
Chapter: [0.011000000000000001] Raoult's law and colligative properties
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Define azeotropes. 

[0.011000000000000001] Raoult's law and colligative properties
Chapter: [0.011000000000000001] Raoult's law and colligative properties
Concept: undefined > undefined
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