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प्रश्न
Account for the following:
Gabriel phthalimide synthesis is preferred for synthesising primary amines.
उत्तर
Gabriel phthalimide synthesis is preferred for synthesising primary amines:
Gabriel phthalimide synthesis results in the formation of 1° amine only. 2° or 3° amines are not formed in this synthesis. Thus, a pure 1° amine can be obtained. Therefore, Gabriel phthalimide synthesis is preferred for synthesizing primary amines.
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संबंधित प्रश्न
Identify the weakest base amongst the following :
(a) p- methoxyaniline
(b) o-toluidine
(c) benzene - 1, 4 - diamine
(d) 4 - aminobenzoic acid
Arrange the following in increasing order of their basic strength :
C6H5 – NH2, C6H5 – CH2 – NH2, C6H5 – NH – CH3
How will you convert Benzene into aniline?
Arrange the following in increasing order of their basic strength:
C2H5NH2, C6H5NH2, NH3, C6H5CH2NH2 and (C2H5)2NH
Arrange the following in increasing order of their basic strength:
CH3NH2, (CH3)2NH, (CH3)3N, C6H5NH2, C6H5CH2NH2
Accomplish the following conversion:
Benzene to m-bromophenol
Accomplish the following conversion:
Aniline to p-bromoaniline
Complete the following reactions:
`C_6H_5N_2Cl+H_3PO_2+H_2O->`
Illustrate the following reactions giving suitable example in each case
Ammonolysis
Answer in one sentence.
Arrange the following amines in increasing order of boiling points.
n-propylamine, ethylmethyl amine, trimethylamine.
Tertiary amines have lowest boiling points because ________________
The CORRECT decreasing order of solubility in water will be ____________.
The CORRECT decreasing order of boiling points is:
Among the following isomeric amines, an amine having highest boiling point is:
Which of the following should be most volatile?
Account for the following:
N-ethylethanamine boils at 329.3 K and butanamine boils at 350.8 K, although both are isomeric in nature.
Which of the following have less melting point than amine?
Arrange the following in increasing order of their boiling point:
C2H5OH, C2H5NH2, (C2H5)3N
Write short note on the following:
Ammonolysis