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प्रश्न
Account for the following : There is large difference between the melting and boiling points of oxygen and sulphur.
उत्तर
The oxygen exists as a diatomic molecule, O2, while sulphur exists as a polyatomic molecule, S8. Hence, there is a large difference between the melting point and the boiling point of oxygen and sulphur.
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संबंधित प्रश्न
a. Explain the trends in the following properties with reference to group 16:
1 Atomic radii and ionic radii
2 Density
3 ionisation enthalpy
4 Electronegativity
b. In the electolysis of AgNO3 solution 0.7g of Ag is deposited after a certain period of time. Calulate the quantity of electricity required in coulomb. (Molar mass of Ag is 107.9g mol-1)
Give reasons: SO2 is reducing while TeO2 is an oxidising agent.
List the important sources of sulphur.
Justify the placement of O, S, Se, Te and Po in the same group of the periodic table in terms of electronic configuration, oxidation state and hydride formation.
Knowing the electron gain enthalpy values for O → O− and O → O2− as −141 and 702 kJ mol−1 respectively, how can you account for the formation of a large number of oxides having O2− species and not O−? (Hint: Consider lattice energy factor in the formation of compounds).
Arrange the following in the order of property indicated for each set:
F2, Cl2, Br2, I2 - increasing bond dissociation enthalpy.
Draw the structures of `H_3PO_2`
Give reactions for the following:
O – O single bond is weaker than S – S single bond.
Give a reason for the following:
Fluorine gives only one oxide but chlorine gives a series of oxides.
Strong reducing behaviour of \[\ce{H3PO2}\] is due to ______.
