Advertisements
Advertisements
प्रश्न
An element with density 11.2 g cm–3 forms a f.c.c. lattice with edge length of 4 × 10–8 cm.
Calculate the atomic mass of the element.
(Given : NA = 6.022 × 1023 mol–1)
उत्तर
Given,
Density, d = 11.2 g cm-3
Edge length, a = 4 × 10-8 cm
Avogadro number, NA = 6.022 × 1023
Number of atoms present per unit cell, Z (fcc) = 4
We know for a crystal system,
\[d = \frac{z \times M}{a^3 \times N_A}\]
\[ \Rightarrow M = \frac{d \times a^3 \times N_A}{Z}\]
\[ \Rightarrow M = \frac{11 . 2 \times 64 \times {10}^{- 24} \times 6 . 022 \times {10}^{23}}{4} = 107 . 91 g\]
APPEARS IN
संबंधित प्रश्न
Silver crystallises in FCC structure. If density of silver is 10.51 gcm-3, calculate the volume of unit cell. [Atomic mass of slive (Ag) = 108 gm-1]
Niobium crystallises as body centred cube (BCC) and has density of 8.55 Kg / dm-3 . Calculate the attomic radius of niobium.
(Given : Atomic mass of niobium = 93).
An element with density 10 g cm−3 forms a cubic unit cell with edge length of 3 × 10−8 cm. What is the nature of the cubic unit cell if the atomic mass of the element is 81 g mol−1?
An element with density 2.8 g cm–3 forms a f.c.c. unit cell with edge length 4 x 10–8 cm. Calculate the molar mass of the element.
(Given : NA = 6.022 x 1023 mol –1)
Silver crystallises in fcc lattice. If edge length of the cell is 4.07 × 10−8 cm and density is 10.5 g cm−3, calculate the atomic mass of silver
A metal crystallises into two cubic faces namely face centered (FCC) and body centered (BCC), whose unit cell edge lengths are 3.5 Å and 3.0 Å respectively. Find the ratio of the densities of FCC and BCC.
Represent a cell consisting of Mg2+ | Mg half cell and Ag+
| Ag half cell and write the cell reaction.
( `"E"_("Ag")^° = 0.799 "V", "E"_("Mg")^° = - 2.37 "V"`)
A unit cell of NaCl has 4 formula units. Its edge length is 0.50 nm. Calculate the density if molar mass of NaCl = 58.5 g/mol.
Tetragonal crystal system has the following unit cell dimensions
A unit cell of sodium chloride has four formula units. The edge length of the unit cell is 0.564 nm. The density of sodium chloride is ______ g/cm3.