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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Answer in brief. What is entropy? Give its units. - Chemistry

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प्रश्न

Answer in brief.

What is entropy? Give its units.

टीपा लिहा

उत्तर

  1. Entropy is a measure of molecular disorder or randomness.
  2. An entropy change of a system is equal to the amount of heat transferred (Qrev) to it in a reversible manner divided by the temperature (T) in Kelvin at which the transfer takes place. Thus,
    `triangle "S" = ("Q"_"rev")/"T"`
  3. Units of entropy: J K–1

Note: Entropy or its change ∆S is a state function and depends on the initial and final states of the system and not on the path connecting two states

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Spontaneous (Irreversible) Process
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पाठ 4: Chemical Thermodynamics - Exercises [पृष्ठ ८७]

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बालभारती Chemistry [English] 12 Standard HSC
पाठ 4 Chemical Thermodynamics
Exercises | Q 3.2 | पृष्ठ ८७

संबंधित प्रश्‍न

Answer the following in one or two sentences.

State whether ΔS is positive, negative or zero for the reaction 2H(g)  →  H2(g). Explain.


Answer the following in one or two sentences.

If the enthalpy change of a reaction is ∆H how will you calculate the entropy of surroundings?


Answer the following in one or two sentences.

Comment on the spontaneity of reactions for which ∆H is positive and ∆S is negative.


Answer the following question.

Obtain the relation between ΔG and `triangle "S"_"total"`. Comment on the spontaneity of the reaction.


For a certain reaction ΔH° = 219 kJ and ΔS° = –21 J/K. Determine whether the reaction is spontaneous or nonspontaneous.


Equilibrium constant for a reaction is 20. What is the value of ΔG° at 300 K? (R = 8 x 10-3 kJ)


A system is changed from an initial state to a final state by a manner such that ∆H = Q. If the change from initial state to final state was made by a different path, then ____________.


Identify the INCORRECT statement.


In how many of the following, ∆S is positive?

i. Melting of ice

ii. Sublimation of iodine

iii. Dissolution of CuSO4 in water

iv. Condensation of water vapour

v. Dissociation of H2 molecule into atoms

vi. Conversion of carbon dioxide gas to dry ice

vii. Vaporization of acetone


Which one of the following has ΔS0 greater than zero?


Which of the following conditions indicates the reaction is spontaneous?


At what temperature, a chemical reaction will have the following values of ∆G, ∆S and ∆H?

∆G = −5.2 KJ mol−1, ∆H = 145.6 kJ mol−1, ∆S = −216 kJ mol−1


For a reaction to be non-spontaneous at all temperatures, values of ΔH and ΔS respectively are ____________.


Standard molar entropy is ______.


Calculate the amount of heat liberated during formation of 2. 7 kg of water if heat of formation of water is - 284.5 kJ mol-1.


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The equilibrium constant for a reaction is 10, value of ΔG° at 300 K is (R = 8 × 10-3 kJ)


For which of the following reaction, ΔH = ΔU?


A reaction is spontaneous at low temperatures but non-spontaneous at high temperatures. Which of the following is true for the reaction?


In which of the following reaction the value of Kp will be equal to Kc?


Identify whether the following pair have larger entropy or not. If yes then Why?

He(g) in a volume of 1 L or He(g) in a volume of 5 L both at 25°C.


Identify whether the following pair have a larger entropy or not. If yes then Why?

C2H5OH(l) or C2H5OH(g)


Write the relationship between Gibbs energy change for a process and total entropy change of system and surroundings.


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