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प्रश्न
Answer the following question based on the P-T phase diagram of carbon dioxide:
What are the critical temperature and pressure for CO2? What is their significance?
उत्तर
The critical temperature and critical pressure of CO2 are 31.1°C and 73 atm respectively. Even if it is compressed to a pressure greater than 73 atm, CO2 will not liquefy above the critical temperature.
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संबंधित प्रश्न
A copper block of mass 2.5 kg is heated in a furnace to a temperature of 500 °C and then placed on a large ice block. What is the maximum amount of ice that can melt? (Specific heat of copper = 0.39 J g–1 K–1; heat of fusion of water = 335 J g–1).
Answer the following questions based on the P–T phase diagram of CO2:
What happens when CO2 at 4 atm pressure is cooled from room temperature at constant pressure?
Answer the following questions based on the P–T phase diagram of CO2:
Describe qualitatively the changes in a given mass of solid CO2 at 10 atm pressure and temperature –65 °C as it is heated up to room temperature at constant pressure.
Answer the following questions based on the P–T phase diagram of CO2:
CO2 is heated to a temperature 70 °C and compressed isothermally. What changes in its properties do you expect to observe?
A ‘thermacole’ icebox is a cheap and efficient method for storing small quantities of cooked food in summer in particular. A cubical icebox of side 30 cm has a thickness of 5.0 cm. If 4.0 kg of ice is put in the box, estimate the amount of ice remaining after 6 h. The outside temperature is 45 °C, and coefficient of thermal conductivity of thermacole is 0.01 J s–1 m–1 K–1. [Heat of fusion of water = 335 × 103 J kg–1]
A brass boiler has a base area of 0.15 m2 and thickness 1.0 cm. It boils water at the rate of 6.0 kg/min when placed on a gas stove. Estimate the temperature of the part of the flame in contact with the boiler. The thermal conductivity of brass = 109 J s –1 m–1 K–1; Heat of vaporisation of water = 2256 × 103 J kg–1.
A metal block of heat capacity 80 J°C−1 placed in a room at 20°C is heated electrically. The heater is switched off when the temperature reaches 30°C. The temperature of the block rises at the rate of 2°C s−1 just after the heater is switched on and falls at the rate of 0.2°C s−1 just after the heater is switched off. Assume Newton's law of cooling to hold.
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- Assuming that the power radiated at 25°C represents the average value in the heating process, find the time for which the heater was kept on.
Answer the following question based on the P-T phase diagram of carbon dioxide:
At what temperature and pressure can the solid, liquid and vapour phases of CO2 co-exist in equilibrium?
Mark the correct options:
- A system X is in thermal equilibrium with Y but not with Z. System Y and Z may be in thermal equilibrium with each other.
- A system X is in thermal equilibrium with Y but not with Z. Systems Y and Z are not in thermal equilibrium with each other.
- A system X is neither in thermal equilibrium with Y nor with Z. The systems Y and Z must be in thermal equilibrium with each other.
- A system X is neither in thermal equilibrium with Y nor with Z. The system Y and Z may be in thermal equilibrium with each other.
100 g of water is supercooled to –10°C. At this point, due to some disturbance mechanised or otherwise some of it suddenly freezes to ice. What will be the temperature of the resultant mixture and how much mass would freeze?
`[S_w = 1cal/g/^circC and L_(Fusion)^w = 80cal/g]`
