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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Consider the half reactions with standard potentials. i. AgA(aq)⊕+eA⊖⟶AgA(s)EA∘= 0.8V ii. IA2A(s)+2eA⊖⟶2IA⊖A(aq) EA∘= 0.53V iii. PbA2⊕A(aq)+2eA⊖⟶PbA(s) EA∘=−0.13V iv. FeA2⊕+2eA⊖⟶FeA(s) EA∘=−0.44V The - Chemistry

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प्रश्न

Consider the half reactions with standard potentials.

  1. \[\ce{Ag^{\oplus}_{ (aq)} + e^{\ominus} -> Ag_{(s)}E^\circ = 0.8 V}\] 
  2. \[\ce{I2_{(s)} + 2e^\ominus -> 2I^{\ominus}_{(aq)} E^\circ = 0.53V}\]
  3. \[\ce{Pb^{2\oplus}_{(aq)} + 2e^{\ominus} -> Pb_{(s)} E^\circ = -0.13 V}\]
  4. \[\ce{Fe^{2\oplus} + 2e^{\ominus} -> Fe_{(s)} E^\circ = -0.44 V}\]

The strongest oxidising  and reducing agents respectively are ______.

पर्याय

  • \[\ce{Ag and Fe^{2\oplus}}\]

  • \[\ce{Ag^{\oplus} and Fe}\]

  • \[\ce{Pb^{2\oplus} and I}\]

  • \[\ce{I2 and Fe^{2\oplus}}\]

MCQ
रिकाम्या जागा भरा

उत्तर

The strongest oxidising  and reducing agents respectively are \[\ce{Ag^{\oplus} and Fe}\].

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Electrode Potential and Cell Potential
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पाठ 5: Electrochemistry - Exercises [पृष्ठ ११७]

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बालभारती Chemistry [English] 12 Standard HSC
पाठ 5 Electrochemistry
Exercises | Q 1.06 | पृष्ठ ११७

संबंधित प्रश्‍न

Answer the following:

Calculate emf of the cell:

Zn(s) |Zn2+ (0.2 M)||H+ (1.6 M)| H2(g, 1.8 atm)| Pt at 25 °C.


Answer the following:

Predict whether the following reaction would occur spontaneously under standard state condition.

`2"Br"_(("aq"))^(-) + "Sn"_(("aq"))^(2+) -> "Br"_(2("l")) + "Sn"_(("s"))`


What is cell voltage?


Calculate the voltage of the cell Sn(s) / Sn2+(0.02 M) // Ag+ (0.01 M) / Ag(s) at 25 °C.

Given: `"E"_"Sn"^circ` = - 0.136, `"E"_"Ag"^circ` = 0.800 V


Calculate `"E"_"cell"^circ` of the following galvanic cell:

Mg(s) / Mg2+(1 M) // Ag+ (1 M) / Ag(s) if `"E"_"Mg"^circ` = – 2.37 V and `"E"_"Ag"^circ` = 0.8 V. Write cell reactions involved in the above cell. Also mention if cell reaction is spontaneous or not.


Standard reduction electrode potentials of three metals A, B and C are +0.5 V, −3.0 V and −1.2 V respectively. The order of reducing powers of these metals is ____________.


Calculate E.M.F. of following cell at 298 K Zn(s) |ZnSO4 (0.01 M)| |CuSO4 (1.0 M)| Cu(s) if \[\ce{E^0_{cell}}\] = 2.0 V.


Calculate \[\ce{E^0_{cell}}\] for the following cell.

\[\ce{Cr_{(s)} | Cr^{3+}_{( aq)} || Fe^{2+}){( aq)} | Fe_{(s)}}\]

Given: `"E"_("Cr"^(3+)//"Cr")^0` = −0.74 V,

`"E"_("Fe"^(2+)//"Fe")^0` = −0.44 V


The reduction potential of a half-cell consisting of nickel electrode in 0.1 M NiSO4 solution at 25°C is ____________.

(E0 = −0.257 V)


Identify the strongest reducing agent from the data given below:

Element `"E"^0 ("V")`
Al −1.66
Fe −0.44
Hg +0.79
Cu +0.337

What is the standard emf of the following cell?

\[\ce{Ni_{(s)} | Ni^{2+}_{( aq)} || Au^{3+}_{( aq)} | Au_{(s)}}\]

if \[\ce{E^0_{Ni}}\] = −0.25 V, \[\ce{E^0_{Au}}\] = 1.50 V.


What is the ΔG0 for the following reaction?

\[\ce{Al_{(s)} + Fe^{3+}_{( aq)} -> Al^{3+}_{( aq)} + Fe_{(s)}}\]; \[\ce{E^0_{cell}}\] = +2.43


The standard electrode potential of Zn and Ni are - 0.76 V and - 0.25 V respectively. If the reaction takes place in the cell constructed between these two electrodes is spontaneous. What is the standard emf of the cell?


The tendency of an electrode to lose electrons is known as ______


The standard potential of the cell in the following reaction is ______.

\[\ce{Cd_{(s)} + Cu^{2+}_{(1M)} -> Cd^{2+}_{(1M)} + Cu_{(s)}}\]

`("E"_("Cd")^circ = - 0.403V, "E"_("Cu")^circ = 0.334V)`


Construct a cell from Ni2+ | Ni and Cu2+ | Cu Cu half cells. Write the cell reaction and calculate `E_("cell")^0`   
`(E_("Ni")^0 = - 0.236  V and E_("Cu")^0 = + 0.337  V)`


Define standard electrode potential.


The standard potential of the electrode Zn2+(0.02M) |Zn(s) is − 0.76 V. Calculate the electrode potential of the zinc electrode.


Calculate the emf of the following cell at 25°C.

Zn(s)|Zn2+(0.08 M) || Cu2+(0.l M) |Cu(s)

E0zn = − 0.76 V, E0cu = 0.36 V.


Write net cell reaction.


Write the value of `(2.303 RT)/F` in the Nernst equation?


Write the four applications of emf series.


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