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प्रश्न
Give a simple chemical test to distinguish between Aniline and N, N-dimethylaniline
उत्तर १
Aniline is a primary amine while N, N-dimethylaniline is a tertiary amine. They both can be distinguished by Carbylamine test. Primary amines on heating with chloroform and ethanolic potassium hydroxide, form foul-smelling isocyanides or carbylamines. Aniline, being an aromatic primary amine gives positive carbylamine test. However, N, N-dimethylaniline being a tertiary amine does not.
उत्तर २
Carbylamine test can be used to distinguish.
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संबंधित प्रश्न
Which of the following amines yields foul smelling product with holoform and alcoholic KOH?
(a) Ethyl amine
(b) Diethyl amine
(c) Triethyi amine
(d) Ethyl methyl amine
Write the chemical equations involved when aniline is treated with the following reagents:
CHCI3 + KOH
Complete the following reactions :-
`C_6H_5NH_2+CHCl_3 + alc.KOH ->`
Give a balanced equation for the following name reaction:
Carbylamine reaction
Write equations of the following reactions:
Carbyl amine reaction
A primary amine, \[\ce{RNH2}\] can be reacted with \[\ce{CH3-X}\] to get secondary amine, \[\ce{R-NHCH3}\] but the only disadvantage is that 3° amine and quaternary ammonium salts are also obtained as side products. Can you suggest a method where \[\ce{RNH2}\] forms only 2° amine?
Assertion: Acetanilide is less basic than aniline.
Reason: Acetylation of aniline results in decrease of electron density on nitrogen.
What happens when reactions:
Aniline reacts with chloroform in the presence of alcoholic potassium hydroxide
What is the action of the following reagents on ethyl amine?
Chloroform and caustic potash
The reaction of a primary amine with chloroform and ethanolic KOH is called ______.
