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प्रश्न
Name the chloride of a metal which is soluble in excess of ammonium hydroxide. Write equation for the same.
उत्तर १
Zinc chloride (ZnCl2) is soluble in excess of ammonium hydroxide.
\[\ce{\underset{\text{colourless}}{ZnCl2} + 2NH4OH -> \underset{\text{white gelatinous ppt.}}{Zn(OH)2↓} + 2NH4Cl}\]
With excess of NH4OH ppt dissolves
\[\ce{Zn(OH)2 + 2NH4Cl + 2NH4OH(excess) -> \underset{\text{Tetrammine zinc(ll)chloride colourless}}{[Zn(NH3)4]Cl2 + 4H2O}}\]
उत्तर २
It is silver chloride [AgCl] dissolves in excess of NH4OH.
A product formed is [Ag(NH3)2]Cl [Soluble colourless Diamine Argentous (Z) chloride]
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संबंधित प्रश्न
Identify the substance underlined, in the following case
Cation that does not form a precipitate with ammonium hydroxide but forms one with sodium hydroxide
Name the kind of particles present in sodium hydroxide solution.
Name a yellow monoxide that dissolves in hot and concentrated caustic alkali.
Using sodium hydroxide solution, how will you distinguish:
Iron (II) chloride from iron (III) chloride
Write equation for the reaction that will take place when copper sulphate solution is added to sodium hydroxide solution.
State what do you observe when:
Neutral litmus solution is added to alkaline solution
Using Sodium hydroxide solution, how would you distinguish: Iron(II) chloride from Iron (III) chloride
Distinguish by adding:
Sodium hydroxide solution and ammonium hydroxide solution to lead nitrate solution and zinc nitrate solution.
Aqueous lead (II) nitrate can be distinguished from aqueous zinc nitrate by adding any of the following solutions in excess, except:
Name the metal hydroxides which are insoluble in caustic soda solution.
