मराठी

The Transition Metals Show _________ Character Because of the Presence of Unpaired· Electrons and Cu+ is ____________ Because of Its Electronic Configuration is [Ar]3d10 - Chemistry (Theory)

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प्रश्न

The transition metals show _________ character because of the presence of unpaired· electrons and Cu+ is ____________ because of its electronic configuration is [Ar]3d10

उत्तर

The transition metals show paramagnetic character because of the presence of unpaired· electrons and Cu+ is diamagnetic because of its electronic configuration is [Ar]3d10

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2014-2015 (March)

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संबंधित प्रश्‍न

Read the passage given below and answer the following question:

The transition metals when exposed to oxygen at low and intermediate temperatures form thin, protective oxide films of up to some thousands of Angstroms in thickness. Transition metal oxides lie between the extremes of ionic and covalent binary compounds formed by elements from the left or right side of the periodic table. They range from metallic to semiconducting and deviate by both large and small degrees from stoichiometry. Since electron bonding levels are involved, the cations exist in various valence states and hence give rise to a large number of oxides. The crystal structures are often classified by considering a cubic or hexagonal close-packed lattice of one set of ions with the other set of ions filling the octahedral or tetrahedral interstices. The actual oxide structures, however, generally show departures from such regular arrays due in part to distortions caused by packing of ions of different size and to ligand field effects. These distortions depend not only on the number of d-electrons but also on the valence and the position of the transition metal in a period or group.

In the following questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices on the basis of the above passage.

Assertion: Cations of transition elements occur in various valence states.

Reason: Large number of oxides of transition elements are possible.


Why first ionisation enthalpy of Cr is lower than that of Zn?


Match the properties given in Column I with the metals given in Column II.

  Column I (Property) Column II (Metal)
(i)  An element which can show +8 oxidation state (a) \[\ce{Mn}\]
(ii)  3d block element that can show (b) \[\ce{Cr}\]
  upto +7 oxidation state (c) \[\ce{Os}\]
(iii)  3d block element with highest melting point (d) \[\ce{Fe}\]

The orientation of an atomic orbital is governed by


Which of the following maxm magnetic moment?


Agcl is soluble in NH4OH. The solubility is due to the information of:-


Which of the following ions will exhibit colour in aqueous solution?


Consider the following standard electrode potentials (E° in volts) in aqueous solution:

Element M3+/M M+/M
Al - 1.66 +0.55
Tl + 1.26 -0.34

Based on these data, which of the following statements is correct?


Account for the following:

Ce4+ is a strong oxidising agent.


Which of the following ions has the electronic configuration 3d6?
(Atomic number: Mn = 25, Co = 27, Ni = 28)


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