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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

What is meant by the following term? Give an example of the reaction in the following case. Hemiacetal - Chemistry

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प्रश्न

What is meant by the following term? Give an example of the reaction in the following case.

Hemiacetal

रासायनिक समीकरणे/रचना
अति संक्षिप्त उत्तर

उत्तर

Gem-alkoxyalcohols are called hemiacetals. These are produced when a molecule of monohydric alcohol combines with an aldehyde in the presence of dry HCl gas.

\[\begin{array}{cc}
\ce{H3C}\phantom{.........................}\ce{CH3}\phantom{....}\ce{OH}\\
\backslash\phantom{...........................}\backslash\phantom{...}/\\
\ce{C = O + H - OCH3 <=>[Dry HCl_{(g)}] C}\\
/\phantom{...........................}/\phantom{...}\backslash\\
\phantom{....}\ce{H}\phantom{...........................}\ce{\underset{Hemiacetal}{H\phantom{....}OCH3}}\
\end{array}\]

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पाठ 12: Aldehydes, Ketones and Carboxylic Acids - Exercises [पृष्ठ ३७७]

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एनसीईआरटी Chemistry [English] Class 12
पाठ 12 Aldehydes, Ketones and Carboxylic Acids
Exercises | Q 1 (v) | पृष्ठ ३७७

संबंधित प्रश्‍न

Acetaldehyde, when treated with which among the following reagents does NOT undergo addition reaction?

(A) Ammonia

(B) Hydroxylamine

(C) Ammoniacal silver nitrate

(D) Semicarbazide


How are the following compounds prepared?

benzaldehyde from benzene


Predict the product of the following reaction:


Predict the product of the following reaction:


What is meant by the following term? Give an example of the reaction in the following case.

Cyanohydrin


What is meant by the following term? Give an example of the reaction in the following case.

Oxime


What is meant by the following term? Give an example of the reaction in the following case.

Imine


Give plausible explanation for the following:

There are two −NH2 groups in semicarbazide. However, only one is involved in the formation of semicarbazones.


How are the following compounds prepared?

benzaldehyde from benzoyl chloride


Benzaldehyde can be obtained from benzal chloride. Write reactions for obtaining benzalchloride and then benzaldehyde from it.


Write the name of product formed, when acetone is treated with 2, 4-dinitrophenyl hydrazine.


Arrange the following in the increasing order of their property indicated:

Ethanal, Propanone, Propanal, Butanone (reactivity towards nucleophilic addition)


Which will undergo faster nucleophilic addition reaction?

Acetaldehyde or Propanone


Aldehydes and ketones react with hydroxylamine to form ______.


Draw structure of the following derivative.

The ethylene ketal of hexan-3-one


Draw the structure of the following derivative.

Acetaldehydedimethylacetal


Draw structure of the following derivative.

The ethylene ketal of hexan-3-one


Give an example of the reaction in the following case.

Oxime


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