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प्रश्न
Which of the following hydrocarbons can decolourise bromine water and which cannot? Why?
C6H12, C6H14, C6H10
उत्तर
C6H12 (Hexene) and C6H10 (Hexyne or Cyclohexene ) are the hydrocarbons which can decolourize bromine water, as they are unsaturated. Bromine undergo addition reactions with unsaturated compounds like alkenes and alkynes containing a double or a triple bond. When bromine water is added to an unsaturated compound, the former gets added to the latter, thereby turning colourless from its reddish brown colour.
C6H14 (Hexane) is a hydrocarbon which cannot decolourize bromine water because it is a saturated compound (alkane). Saturated co
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- \[\begin{array}{cc}
\ce{H}\phantom{...}\ce{H}\phantom{...}\ce{H}\phantom{..}\\
\phantom{}|\phantom{....}|\phantom{....}|\phantom{..}\\
\ce{H - C - C - C - OH}\\
\phantom{}|\phantom{....}|\phantom{....}|\phantom{..}\\
\ce{H}\phantom{...}\ce{H}\phantom{...}\ce{H}\phantom{..}\\
\end{array}\] - \[\begin{array}{cc}
\phantom{...}\ce{H}\phantom{...}\ce{H}\phantom{...}\ce{H}\phantom{....}\\
\phantom{...}|\phantom{....}|\phantom{....}||\phantom{....}\\
\ce{H - C - C - C - OH}\\
\phantom{...}|\phantom{....}|\phantom{.........}\\
\phantom{}\ce{H}\phantom{...}\ce{H}\phantom{.......}\\
\end{array}\] - \[\begin{array}{cc}
\phantom{......}\ce{H}\phantom{....}\ce{H}\phantom{....}\ce{O}\phantom{...}\ce{H}\phantom{...}\ce{H}\phantom{.......}\\
\phantom{....}|\phantom{....}|\phantom{....}||\phantom{....}|\phantom{....}|\phantom{....}\\
\ce{H} - \ce{C} - \ce{C} - \ce{C} - \ce{C} - \ce{C} - \ce{H}\\
\phantom{....}|\phantom{.....}|\phantom{........}|\phantom{....}|\phantom{....}\\
\phantom{....}\ce{H}\phantom{....}\ce{H}\phantom{........}\ce{H}\phantom{..}\ce{H}\phantom{.....}\\
\end{array}\] - \[\begin{array}{cc}
\phantom{......}\ce{H}\phantom{...}\ce{H}\phantom{...}\ce{H}\phantom{...}\ce{H}\phantom{......}\\
\phantom{....}|\phantom{....}|\phantom{....}|\phantom{....}|\phantom{....}\\
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\phantom{....}|\phantom{....}|\phantom{.............}\\
\phantom{....}\ce{H}\phantom{...}\ce{H}\phantom{.............}
\end{array}\]
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\ce{CH3}\phantom{.....}\ce{CH3}\phantom{.........}\ce{CH3}\phantom{..}\ce{CH3}\phantom{..........}\\
\phantom{...}\backslash\phantom{......}/\phantom{................}|\phantom{.....}|\phantom{............}\\
\ce{C} = \ce{C} + \ce{H2} \overset{\ce{Ni}}{\rightarrow} \ce{CH3 - C - C - CH3}\\
\phantom{.}/\phantom{........}\backslash\phantom{..............}|\phantom{....}|\phantom{.........}\\
\ce{CH3}\phantom{....}\ce{CH3}\phantom{............}\ce{H}\phantom{...}\ce{H}\phantom{........}
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\[\begin{array}{cc}
\phantom{}\ce{H}\phantom{...}\ce{H}\phantom{...}\ce{H}\phantom{.....}\\
\phantom{}|\phantom{....}|\phantom{....}|\phantom{.....}\\
\ce{H} - \ce{C} - \ce{C} - \ce{C} ≡ \ce{C} - \ce{H}\\
\phantom{}|\phantom{....}|\phantom{..........}\\
\phantom{}\ce{H}\phantom{...}\ce{H}\phantom{..........}\\
\end{array}\]
