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प्रश्न
Write the free radical mechanism for the polymerisation of ethene.
उत्तर
Polymerization of ethene to polythene consists of heating or exposing to light a mixture of ethene with a small amount of benzoyl peroxide as the initiator.
The reaction involved in this process is given below:
Chain terminating step
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संबंधित प्रश्न
How are polythene and neoprene prepared?
Write the molecular formula and structural formula of BHA and BHT.
What is the role of t-butyl peroxide in the polymerization of ethene?
Write the mechanism of free radical polymerization of ethene.
Out of chain growth polymerisation and step growth polymerisation, in which type will you place the following.
What is the role of benzoyl peroxide in addition polymerisation of alkenes? Explain its mode of action with the help of an example.
Match the polymer of column I with correct monomer of column II.
| Column I | Column II |
| (i) High density polythene | (a) Isoprene |
| (ii) Neoprene | (b) Tetrafluoroethene |
| (iii) Natural rubber | (c) Chloroprene |
| (iv) Teflon | (d) Acrylonitrile |
| (v) Acrilan | (e) Ethene |
Match the polymers given in Column I with the preferred mode of polymerisation followed by their monomers.
| Column I | Column II |
| (i) Nylon-6,6 | (a) Free radical polymerisation |
| (ii) PVC | (b) Ziegler-Natta polymerisation or coordination polymerisation |
| (iii) HDP | (c) Anionic polymerisation |
| (d) Condensation polymerisation |
Assertion: Olefinic monomers undergo addition polymerisation.
Reason: Polymerisation of vinyl chloride is initiated by peroxides/ persulphates.
Low density polythene and high density polythene, both are polymers of ethene but there is marked difference in their properties. Explain.
Which one of the following can be used as monomer in a polymerisation reaction?
The Ziegler Natta catalyst are
Which of the following is chain-growth polymer?
\[\ce{X + C + Cl2 ->[High temperature][of about 1000 K] Y + CO}\];
\[\ce{Y + 2H2O -> Z + 2HCl}\]
Compound Y is found in polymeric chain structure and is an electron-deficient Molecule. Y must be:
