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A liquid with high boiling point decomposes on simple distillation but it can be steam distilled for its purification. Explain how is it possible? - Chemistry

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Question

A liquid with high boiling point decomposes on simple distillation but it can be steam distilled for its purification. Explain how is it possible?

Long Answer

Solution

Steam distillation is a special type of separation technique for temperature-sensitive materials such as natural organic compounds. Few organic compounds tend to decompose at higher temperatures and normal distillation does not fit for this purpose. So, water is added to the apparatus and the temperature of the compounds is depressed, evaporating them at lower temperature. Once the distillation is accomplished, the vapours are condensed and there occurs, the separation of the constituents at ease.

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Introduction of Methods of Purification of Organic Compounds
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Chapter 12: Organic Chemistry Some Basic Principles and Techniques - Multiple Choice Questions (Type - I) [Page 156]

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NCERT Exemplar Chemistry [English] Class 11
Chapter 12 Organic Chemistry Some Basic Principles and Techniques
Multiple Choice Questions (Type - I) | Q 66 | Page 156

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