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Account for the Following : Sulphur in Vapour Form Exhibits Paramagnetic Behaviour. - Chemistry

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Question

Account for the following :

Sulphur in vapour form exhibits paramagnetic behaviour.

Solution

Sulphur partly exists as S2 molecule in vapour state, which has two unpaired electrons in the antibonding

\[\pi^*\] molecular orbitals and hence, it exhibits paramagnetism.
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2013-2014 (March) Delhi Set 3

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