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Which of the following options are not in accordance with the property mentioned against them? (i) FX2>ClX2>BrX2>IX2 Oxidising power (ii) MI>MBr>MCX1>MF Ionic character of metal halide. (iii) FX2>C - Chemistry

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Question

Which of the following options are not in accordance with the property mentioned against them?

(i) \[\ce{F2 > Cl2 > Br2 > I2}\]  Oxidising power.
(ii) \[\ce{MI > MBr > MC1 > MF}\]   Ionic character of metal halide.
(iii) \[\ce{F2 > Cl2 > Br2 > I2}\]   Bond dissociation enthalpy.
(iv) \[\ce{HI < HBr < HCI < HF}\] Hydrogen-halogen bond strength.
Short Note

Solution

(ii) \[\ce{MI > MBr > MC1 > MF}\]   Ionic character of metal halide.
(iii) \[\ce{F2 > Cl2 > Br2 > I2}\]   Bond dissociation enthalpy.

Explanation:

Bond dissociation enthalpy order is \[\ce{Cl2 > Br2 > F2 > l2}\]

Ionic character of metal reases as electronegativity of halogen increases  \[\ce{Ml < MBr < Mcl < MF}\]

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Chapter 7: The p-block Elements - Multiple Choice Questions (Type - I) [Page 95]

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NCERT Exemplar Chemistry [English] Class 12
Chapter 7 The p-block Elements
Multiple Choice Questions (Type - I) | Q 29 | Page 95

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