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Assertion (A): H2S is less acidic than H2Te. Reason (R): H-S bond has more Δbond H° than H-Te bond. - Chemistry

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Question

Assertion (A): H2S is less acidic than H2Te.

Reason (R): H-S bond has more Δbond H° than H-Te bond.

Options

  • Both A and R are true and R is the correct explanation of A.

  • Both A and R are true but R is not the correct explanation of A.

  • A is true but R is false.

  • A is false but R is true.

MCQ
Assertion and Reasoning

Solution

Both A and R are true but R is not the correct explanation of A.

Explanation:

The acidity of hydrides increases down the group because the bond strength between hydrogen and the central atom decreases, making it easier to release H+. In H2S the H - S bond has a higher bond dissociation enthalpy (Δbond H°) compared to the weaker H - Te bond in H2Te which makes H2Te more acidic. Hence, the reason correctly explains the assertion.

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2021-2022 (December) Term 1
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