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Calculate magnetic moment of thorium (Z=90). Is this element diamagnetic or paramagnetic? - Chemistry

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Question

Calculate magnetic moment of thorium (Z=90). Is this element diamagnetic or paramagnetic?

Short Note

Solution

The electronic configuration of thorium is [Rn] 5f0 6d2 7s2.

the condensed electronic configuration for its divalent cation will be

There are 2 unpaired electrons, so n = 2.

`therefore mu = sqrt(2 (2 + 2)) = sqrt8` BM = 2.83 BM

Spin only magnetic moment of the given ion is 2.83 BM. This element contains two unpaired electrons and hence, it is paramagnetic.

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Trends in Atomic Properties of the First Transition Series
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Chapter 8: Transition and Inner transition Elements - Short Answer Questions (Type-II)

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SCERT Maharashtra Chemistry [English] 12 Standard HSC
Chapter 8 Transition and Inner transition Elements
Short Answer Questions (Type-II) | Q 3

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