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Question
Concentration of the Ag+ ions in a saturated solution of Ag2C2O4 is 2.24 × 10−4 mol L−1 solubility product of Ag2C2O4 is ____________.
Options
2.24 × 10−8 mol3 L−3
2.66 × 10−12 mol3 L−3
4.5 × 10−11 mol3 L−3
5.619 × 10−12 mol3 L−3
Solution
Concentration of the Ag+ ions in a saturated solution of Ag2C2O4 is 2.24 × 10−4 mol L−1 solubility product of Ag2C2O4 is 5.619 × 10−12 mol3 L−3.
Explanation:
\[\ce{Ag2C2O4 ⇌ 2Ag^+ + C2O^{2-}_4}\]
[Ag+] = 2.24 × 10−4 mol L−1
\[\ce{[C2O^{2-}_4]}\] = `(2.24 xx 10^-4)/2` mol L−1
= 1.12 × 10−4 mol L−1
Ksp = \[\ce{[Ag^+]^2 [C2O^{2-}_4]}\]
= (2.24 × 10−4 mol L−1)2 (1.12 × 10−4 mol L−1)
= 5.619 × 10−12 mol3 L−3
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