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Distinguish Between Isothermal Process and Adiabatic Process. - Chemistry

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Question

Distinguish between isothermal process and adiabatic process.

Solution

No Isothermal process Adiabatic process
1 The temperature of system remains
constant (ΔT = 0).
The temperature of system changes i.e.
increases or decreases (ΔT ≠0).
2 System can exchange heat with the surroundings (q ≠ 0). System cannot exchange heat with the surroundings (q = 0).
3 The internal energy of the system
remains constant (ΔU = 0).
The internal energy of the system changes
(ΔU ≠ 0).
4 System is not thermally isolated from its  surroundings.  Hence, open or closed system is required. System is thermally isolated from its surroundings.  Hence, isolated  system is required.
5 In this ΔU = 0, hence q = -W. In this q = 0, hence ΔU = W.
6 Enthalpy remains constant (ΔH = 0). Enthalpy changes in this process (ΔH ≠ 0).
7 Expansion takes place by absorbing
heat from  surroundings
Expansion takes place by utilizing internal energy of the system
8 Heat supplied is used only for doing
work.
Work done is only at the cost of internal energy.
9 Compression takes place by  losing heat to the surroundings.  Compression takes place by adding heat
into internal energy of the system.
10 Fusion of ice. Expansion of gas in vacuum.
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2016-2017 (July)

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