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Chemistry 2016-2017 HSC Science (General) 12th Standard Board Exam Question Paper Solution

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Chemistry
Marks: 70 Maharashtra State Board
HSC Science (General)
HSC Science (Electronics)
HSC Science (Computer Science)

Academic Year: 2016-2017
Date: July 2017
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[7]1 | Select and write the most appropriate answer from the given alternatives for each sub-question:
[1]1.1

Which of the following is a basic oxide?

(A) SiO2

(B) P4O10

(C) MgO

(D) Al2O3

Concept: undefined - undefined
Chapter: [7.01] Group 15 Elements
[1]1.2

In the representation of the galvanic cell, the ions in the same phase are separated by a _______.

single vertical line

comma

double vertical line

semicolon

Concept: undefined - undefined
Chapter: [0.04] Electrochemistry
[1]1.3

An ionic crystal lattice has limiting value of radius ratio as 0.414 to 0.732; the co-ordination number of its cation is _______.

(A) 6

(B) 4

(C) 3

(D) 12

Concept: undefined - undefined
Chapter: [0.01] Solid State
[1]1.4

The unit of rate constant for zero order reaction is _______.

(A) t–1

(B) mol dm–3 t–1

(C) mol–1 dm3 t–1

(D) mol–2 dm6 t–1

Concept: undefined - undefined
Chapter: [0.05] Chemical Kinetics [0.06] Chemical Kinetics
[1]1.5

Calcium carbonate used in the extraction of iron acts as _______.

(A) oxidising agent

(B) reducing agent

(C) gangue

(D) flux

Concept: undefined - undefined
Chapter: [0.06] General Principles and Processes of Isolation of Elements
[1]1.6

10.0 grams of caustic soda when dissolved in 250 cm3 of water, the resultant gram molarity of solution is _______.

(A) 0.25 M

(B) 0.5 M

(C) 1.0 M

(D) 0.1 M

Concept: undefined - undefined
Chapter: [0.04] Electrochemistry
[1]1.7

55 L atm of work is obtained when 1.0 mole of an ideal gas is compressed isothermally from
a volume of 28.5 L to 18.5 L, the constant external pressure is

(A) 5.05 atm

(B) 5.5 atm

(C) 0.05 atm

(D) 0.55 atm

Concept: undefined - undefined
Chapter: [0.03] Chemical Thermodynamics and Energetic
[12]2 | Answer any SIX of the following:
[2]2.1

State Henry’s law.

Concept: undefined - undefined
Chapter: [0.02] Solutions and Colligative Properties

What is the effect of temperature on solubility of a gas in a liquid?

Concept: undefined - undefined
Chapter: [0.02] Solutions and Colligative Properties
[2]2.2

How is nitric acid prepared by Ostwald’s process?

Concept: undefined - undefined
Chapter: [7.01] Group 15 Elements
[2]2.3

Classify the following solids into different types:

a. Ammonium phosphate

b. Brass

c. S8 molecule

d. Diamond

Concept: undefined - undefined
Chapter: [0.01] Solid State [0.01] Solid State
[2]2.4

Construct a labelled diagram for the following cell:

`Zn|Zn^(2+)(1M)||H^+(1M)|H_(2(g,1atm))|Pt`

Concept: undefined - undefined
Chapter: [0.04] Electrochemistry [0.05] Electrochemistry
[2]2.5

Explain the nature of zinc oxide with the help of the reactions.

Concept: undefined - undefined
Chapter: [7.02] Group 16 Elements
[2]2.6

Write the names and chemical formulae of any ‘two’ minerals of aluminium.

Concept: undefined - undefined
Chapter: [0.06] General Principles and Processes of Isolation of Elements
[2]2.7

The rate law for the reaction

`2H_(2(g))+2NO_((g))->N_(2(g))+2H_2O_((g))`

is given by rate= `K[H_2][NO]^2`

The reaction occurs in the following two steps:

a. `H_(2(g)) +2NO_((g))->N_2O_((g))+H_2O_((g))`

b. `N_2O_((g))+H_(2(g))->N_(2(g))+H_2O_((g))`

What is the role of N2O in the mechanism? What is the molecularity of each of the elementary steps?

Concept: undefined - undefined
Chapter:
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[2]2.8

Write mathematical equation of first law of thermodynamics for the following processes :
Adiabatic process.

Concept: undefined - undefined
Chapter: [0.03] Chemical Thermodynamics and Energetic

Write mathematical equation of first law of thermodynamics for Isochoric process. 

Concept: undefined - undefined
Chapter: [0.03] Chemical Thermodynamics and Energetic

Write the mathematical expression of the First Law of Thermodynamics for  Isothermal Process

Concept: undefined - undefined
Chapter: [0.04] Chemical Thermodynamics

Write the mathematical expression of the First Law of Thermodynamics for the Isobaric process.

Concept: undefined - undefined
Chapter: [0.04] Chemical Thermodynamics
[9]3 | Answer any THREE of the following:
[3]3.1

From the following data for the liquid phase reaction A → B, determine the order of reaction
and calculate its rate constant 

t/s 0 600 1200 1800
[A]/`molL^-1` 0.624 0.446 0.318 0.226
Concept: undefined - undefined
Chapter:
[3]3.2

Calculate the standard enthalpy of combustion of CH3COOH(l) from the following data:

`Delta_fH^@(CO_2)=-393.3 kJ mol^-1`

`Delta_fH^@(H_2O)=-285.8 kJ mol^-1`

`Delta_fH^@(CH_3COOH)=-483.2 kJ mol^-1`

Concept: undefined - undefined
Chapter: [0.03] Chemical Thermodynamics and Energetic
[3]3.3

Write the cell representation and calculate equilibrium constant for the following redox reaction:

`Ni_((s))+2Ag_((aq))^+ (1M)->Ni_((aq))^(2+)(1M)+2Ag_((s)) " at "25^@ C`

`E_(ni)^+`=-0.25V and `E_(Ag)^+=0.799V`

Concept: undefined - undefined
Chapter: [0.04] Electrochemistry
[3]3.4

What is the action of concentrated sulphuric acid on phosphorous pentachloride

Concept: undefined - undefined
Chapter: [7.02] Group 16 Elements

What is the action of concentrated sulphuric acid on copper

Concept: undefined - undefined
Chapter: [7.02] Group 16 Elements

What is the action of concentrated sulphuric acid on potassium chlorate?

Concept: undefined - undefined
Chapter: [7.02] Group 16 Elements
[7]4 | Answer any ONE of the following:
[7]4.1

Define Molality.

Concept: undefined - undefined
Chapter: [0.02] Solutions and Colligative Properties

Define osmotic pressure.

Concept: undefined - undefined
Chapter: [0.02] Solutions [0.02] Solutions and Colligative Properties

Write any ‘two’ advantages of calomel electrode. 

Concept: undefined - undefined
Chapter: [0.04] Electrochemistry

A metal crystallises into two cubic faces namely face centered (FCC) and body centered (BCC), whose unit cell edge lengths are 3.5 Å and 3.0 Å respectively. Find the ratio of the densities of FCC and BCC.

Concept: undefined - undefined
Chapter: [0.01] Solid State

Arrange the following oxyacids of chlorine – HClO, HClO2, HClO3, and HClO4 with respect to Increasing order of thermal stability.

Concept: undefined - undefined
Chapter: [0.07] Elements of Groups 16, 17 and 18 [7.03] Group 17 Elements

Arrange the following oxyacids of chlorine – HClO, HClO2, HClO3, and HClO4 with respect to Increasing order of oxidizing power.

Concept: undefined - undefined
Chapter: [0.07] Elements of Groups 16, 17 and 18 [7.03] Group 17 Elements
[7]4.2

An organic substance (M = 169 gram mol–1) is dissolved in 2000 cm3 of water. Its osmotic pressure at 12°C was found to be 0.54 atm. If R = 0.0821 L atm K–1 mol–1, calculate the mass of the solute.

Concept: undefined - undefined
Chapter: [0.02] Solutions and Colligative Properties

How many atoms constitute one unit cell of a face-centered cubic crystal?

Concept: undefined - undefined
Chapter: [0.01] Solid State

Distinguish between isothermal process and adiabatic process.

Concept: undefined - undefined
Chapter: [0.03] Chemical Thermodynamics and Energetic

Mention the names of various steps involved in the extraction of pure metals from their ores.

Concept: undefined - undefined
Chapter: [0.06] General Principles and Processes of Isolation of Elements
[7]5 | Select and write the most appropriate answer from the given alternatives for each sub-question:
[1]5.1

In the following 

The compound ‘B’ is _______.
(A) Propan–1–amine

(B) Propan–2–amine

(C) Isopropylamine

(D) Dimethylamine

Concept: undefined - undefined
Chapter: [0.13] Amines [13.01] Amines
[1]5.2

The stability order for carbocation is _______.

(A) 2° > 3° > 1° 

(B) 3° > 2° > 1°

(C) 3° > 1° > 2°

(D) 1° > 3° > 2°

Concept: undefined - undefined
Chapter: [10.01] Haloalkanes
[1]5.3

Effective atomic number rule is used to find _______.
(A) geometry of complex
(B) stability of complex
(C) number of isomers of complex
(D) number of possible ligands around metal ion in complex

Concept: undefined - undefined
Chapter: [0.09] Coordination Compounds [0.09] Coordination Compounds
[1]5.4

Which one of the following ions is coloured?

Se3+

Ti4+

Zn2+

V2+

Concept: undefined - undefined
Chapter: [8.01] D-block Elements
[1]5.5

When phenol is heated with conc. HNO3 in presence of conc. H2SO4 it yields _______.

(A) o-nitrophenol

(B) p-nitrophenol

(C) 2,4,6-trinitrophenol

(D) m-nitrophenol

Concept: undefined - undefined
Chapter: [11.02] Phenols
[1]5.6

The secondary structure of protein is determined by _______.

(A) co-ordinate bond

(B) ionic bond

(C) hydrogen bond

(D) covalent bond

Concept: undefined - undefined
Chapter: [14.02] Proteins
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[1]5.7

Ethylidene dichloride when boiled with aqueous solution of NaOH yields _______.

(A) formaldehyde

(B) acetaldehyde

(C) acetone

(D) ethyl methyl ketone

Concept: undefined - undefined
Chapter: [0.11] Alcohols, Phenols and Ethers [11.01] Alcohols [11.02] Phenols [11.03] Ethers
[12]6 | Answer any SIX of the following:
[2]6.1

How is phenol prepared from cumene?

Concept: undefined - undefined
Chapter: [11.02] Phenols
[2]6.2

Write a note on the self oxidation-reduction reaction of an aldehyde with a suitable example.

Concept: undefined - undefined
Chapter: [12.01] Aldehydes and Ketones
[2]6.3

Explain basic nature of amines.

Concept: undefined - undefined
Chapter: [13.01] Amines
[2]6.4

Explain the term Antiseptics

Concept: undefined - undefined
Chapter: [16.01] Chemicals in Medicines
[2]6.5

What happens when glucose is treated with hydroxylamine?

Concept: undefined - undefined
Chapter: [14.01] Carbohydrates

What happens when glucose is treated with hydrogen cyanide?

Concept: undefined - undefined
Chapter: [14.01] Carbohydrates
[2]6.6

Draw structure of dichromate ion

Concept: undefined - undefined
Chapter: [8.01] D-block Elements

Draw structure of chromate ion

Concept: undefined - undefined
Chapter: [8.01] D-block Elements
[2]6.7

How is terylene prepared?

Concept: undefined - undefined
Chapter: [0.15] Polymers
[2]6.8

Identify A and B in the following reaction:

`CH_3-Br+Mg"dry ether"/""A+CO_2"dry ether"/(H^+/(H_2O))B+Mg(Br)OH`

Concept: undefined - undefined
Chapter: [10.01] Haloalkanes [10.02] Haloarenes
[3]7 | Answer any THREE of the following:
[3]7.1

How ligands are classified? Explain with suitable examples.

Concept: undefined - undefined
Chapter: [0.09] Coordination Compounds
[3]7.2

What is lanthanoid contraction?

Concept: undefined - undefined
Chapter: [8.02] F-block Elements

Explain, why lanthanum (Z = 57) forms La3+ ion, while cerium (Z = 58) forms Ce4+ ion?

Concept: undefined - undefined
Chapter: [8.02] F-block Elements
[3]7.3

What is the action of phenyl hydrazine on propanone?

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids [12.01] Aldehydes and Ketones

What is the action of Zn – Hg / conc. HCl on propanone?

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids [12.01] Aldehydes and Ketones

What is the action of Sodium bisulphite on propanone?

Concept: undefined - undefined
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids [12.01] Aldehydes and Ketones
[3]7.4

Define enzymes.

Concept: undefined - undefined
Chapter: [14.02] Proteins

How is peptide linkage formed?

Concept: undefined - undefined
Chapter: [14.02] Proteins
[7]8 | Answer any ONE of the following:
[7]8.1

How is nitroethane converted into ethylamine.

Concept: undefined - undefined
Chapter: [11.03] Ethers

How is nitroethane converted into N-ethylhydroxylamine

Concept: undefined - undefined
Chapter: [11.03] Ethers

How is nitroethane converted into acetic acid

Concept: undefined - undefined
Chapter: [11.03] Ethers

Write names and chemical formulae of monomers used in preparing Buna-N.

Concept: undefined - undefined
Chapter: [0.15] Polymers

What is a soap ?

Concept: undefined - undefined
Chapter: [16.03] Cleansing Agents

How soap is prepared?

Concept: undefined - undefined
Chapter: [16.03] Cleansing Agents
[7]8.2

How will you prepare ethanol, propan-2-ol and 2-methylpropan-2-ol from Grignard’s reagent?

Concept: undefined - undefined
Chapter: [11.01] Alcohols

Explain  Optical activity

Concept: undefined - undefined
Chapter: [0.09] Coordination Compounds

Explain optical activity of lactic acid

Concept: undefined - undefined
Chapter: [0.09] Coordination Compounds

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