HSC Science (General)
HSC Science (Electronics)
HSC Science (Computer Science)
Academic Year: 2016-2017
Date: July 2017
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Which of the following is a basic oxide?
(A) SiO2
(B) P4O10
(C) MgO
(D) Al2O3
Chapter: [7.01] Group 15 Elements
In the representation of the galvanic cell, the ions in the same phase are separated by a _______.
single vertical line
comma
double vertical line
semicolon
Chapter: [0.04] Electrochemistry
An ionic crystal lattice has limiting value of radius ratio as 0.414 to 0.732; the co-ordination number of its cation is _______.
(A) 6
(B) 4
(C) 3
(D) 12
Chapter: [0.01] Solid State
The unit of rate constant for zero order reaction is _______.
(A) t–1
(B) mol dm–3 t–1
(C) mol–1 dm3 t–1
(D) mol–2 dm6 t–1
Chapter: [0.05] Chemical Kinetics [0.06] Chemical Kinetics
Calcium carbonate used in the extraction of iron acts as _______.
(A) oxidising agent
(B) reducing agent
(C) gangue
(D) flux
Chapter: [0.06] General Principles and Processes of Isolation of Elements
10.0 grams of caustic soda when dissolved in 250 cm3 of water, the resultant gram molarity of solution is _______.
(A) 0.25 M
(B) 0.5 M
(C) 1.0 M
(D) 0.1 M
Chapter: [0.04] Electrochemistry
55 L atm of work is obtained when 1.0 mole of an ideal gas is compressed isothermally from
a volume of 28.5 L to 18.5 L, the constant external pressure is
(A) 5.05 atm
(B) 5.5 atm
(C) 0.05 atm
(D) 0.55 atm
Chapter: [0.03] Chemical Thermodynamics and Energetic
State Henry’s law.
Chapter: [0.02] Solutions and Colligative Properties
What is the effect of temperature on solubility of a gas in a liquid?
Chapter: [0.02] Solutions and Colligative Properties
How is nitric acid prepared by Ostwald’s process?
Chapter: [7.01] Group 15 Elements
Classify the following solids into different types:
a. Ammonium phosphate
b. Brass
c. S8 molecule
d. Diamond
Chapter: [0.01] Solid State [0.01] Solid State
Construct a labelled diagram for the following cell:
`Zn|Zn^(2+)(1M)||H^+(1M)|H_(2(g,1atm))|Pt`
Chapter: [0.04] Electrochemistry [0.05] Electrochemistry
Explain the nature of zinc oxide with the help of the reactions.
Chapter: [7.02] Group 16 Elements
Write the names and chemical formulae of any ‘two’ minerals of aluminium.
Chapter: [0.06] General Principles and Processes of Isolation of Elements
The rate law for the reaction
`2H_(2(g))+2NO_((g))->N_(2(g))+2H_2O_((g))`
is given by rate= `K[H_2][NO]^2`
The reaction occurs in the following two steps:
a. `H_(2(g)) +2NO_((g))->N_2O_((g))+H_2O_((g))`
b. `N_2O_((g))+H_(2(g))->N_(2(g))+H_2O_((g))`
What is the role of N2O in the mechanism? What is the molecularity of each of the elementary steps?
Chapter:
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Write mathematical equation of first law of thermodynamics for the following processes :
Adiabatic process.
Chapter: [0.03] Chemical Thermodynamics and Energetic
Write mathematical equation of first law of thermodynamics for Isochoric process.
Chapter: [0.03] Chemical Thermodynamics and Energetic
Write the mathematical expression of the First Law of Thermodynamics for Isothermal Process
Chapter: [0.04] Chemical Thermodynamics
Write the mathematical expression of the First Law of Thermodynamics for the Isobaric process.
Chapter: [0.04] Chemical Thermodynamics
From the following data for the liquid phase reaction A → B, determine the order of reaction
and calculate its rate constant
t/s | 0 | 600 | 1200 | 1800 |
[A]/`molL^-1` | 0.624 | 0.446 | 0.318 | 0.226 |
Chapter:
Calculate the standard enthalpy of combustion of CH3COOH(l) from the following data:
`Delta_fH^@(CO_2)=-393.3 kJ mol^-1`
`Delta_fH^@(H_2O)=-285.8 kJ mol^-1`
`Delta_fH^@(CH_3COOH)=-483.2 kJ mol^-1`
Chapter: [0.03] Chemical Thermodynamics and Energetic
Write the cell representation and calculate equilibrium constant for the following redox reaction:
`Ni_((s))+2Ag_((aq))^+ (1M)->Ni_((aq))^(2+)(1M)+2Ag_((s)) " at "25^@ C`
`E_(ni)^+`=-0.25V and `E_(Ag)^+=0.799V`
Chapter: [0.04] Electrochemistry
What is the action of concentrated sulphuric acid on phosphorous pentachloride
Chapter: [7.02] Group 16 Elements
What is the action of concentrated sulphuric acid on copper
Chapter: [7.02] Group 16 Elements
What is the action of concentrated sulphuric acid on potassium chlorate?
Chapter: [7.02] Group 16 Elements
Define Molality.
Chapter: [0.02] Solutions and Colligative Properties
Define osmotic pressure.
Chapter: [0.02] Solutions [0.02] Solutions and Colligative Properties
Write any ‘two’ advantages of calomel electrode.
Chapter: [0.04] Electrochemistry
A metal crystallises into two cubic faces namely face centered (FCC) and body centered (BCC), whose unit cell edge lengths are 3.5 Å and 3.0 Å respectively. Find the ratio of the densities of FCC and BCC.
Chapter: [0.01] Solid State
Arrange the following oxyacids of chlorine – HClO, HClO2, HClO3, and HClO4 with respect to Increasing order of thermal stability.
Chapter: [0.07] Elements of Groups 16, 17 and 18 [7.03] Group 17 Elements
Arrange the following oxyacids of chlorine – HClO, HClO2, HClO3, and HClO4 with respect to Increasing order of oxidizing power.
Chapter: [0.07] Elements of Groups 16, 17 and 18 [7.03] Group 17 Elements
An organic substance (M = 169 gram mol–1) is dissolved in 2000 cm3 of water. Its osmotic pressure at 12°C was found to be 0.54 atm. If R = 0.0821 L atm K–1 mol–1, calculate the mass of the solute.
Chapter: [0.02] Solutions and Colligative Properties
How many atoms constitute one unit cell of a face-centered cubic crystal?
Chapter: [0.01] Solid State
Distinguish between isothermal process and adiabatic process.
Chapter: [0.03] Chemical Thermodynamics and Energetic
Mention the names of various steps involved in the extraction of pure metals from their ores.
Chapter: [0.06] General Principles and Processes of Isolation of Elements
In the following
The compound ‘B’ is _______.
(A) Propan–1–amine
(B) Propan–2–amine
(C) Isopropylamine
(D) Dimethylamine
Chapter: [0.13] Amines [13.01] Amines
The stability order for carbocation is _______.
(A) 2° > 3° > 1°
(B) 3° > 2° > 1°
(C) 3° > 1° > 2°
(D) 1° > 3° > 2°
Chapter: [10.01] Haloalkanes
Effective atomic number rule is used to find _______.
(A) geometry of complex
(B) stability of complex
(C) number of isomers of complex
(D) number of possible ligands around metal ion in complex
Chapter: [0.09] Coordination Compounds [0.09] Coordination Compounds
Which one of the following ions is coloured?
Se3+
Ti4+
Zn2+
V2+
Chapter: [8.01] D-block Elements
When phenol is heated with conc. HNO3 in presence of conc. H2SO4 it yields _______.
(A) o-nitrophenol
(B) p-nitrophenol
(C) 2,4,6-trinitrophenol
(D) m-nitrophenol
Chapter: [11.02] Phenols
The secondary structure of protein is determined by _______.
(A) co-ordinate bond
(B) ionic bond
(C) hydrogen bond
(D) covalent bond
Chapter: [14.02] Proteins
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Ethylidene dichloride when boiled with aqueous solution of NaOH yields _______.
(A) formaldehyde
(B) acetaldehyde
(C) acetone
(D) ethyl methyl ketone
Chapter: [0.11] Alcohols, Phenols and Ethers [11.01] Alcohols [11.02] Phenols [11.03] Ethers
How is phenol prepared from cumene?
Chapter: [11.02] Phenols
Write a note on the self oxidation-reduction reaction of an aldehyde with a suitable example.
Chapter: [12.01] Aldehydes and Ketones
Explain the term Antiseptics
Chapter: [16.01] Chemicals in Medicines
What happens when glucose is treated with hydroxylamine?
Chapter: [14.01] Carbohydrates
What happens when glucose is treated with hydrogen cyanide?
Chapter: [14.01] Carbohydrates
Draw structure of dichromate ion
Chapter: [8.01] D-block Elements
Draw structure of chromate ion
Chapter: [8.01] D-block Elements
Identify A and B in the following reaction:
`CH_3-Br+Mg"dry ether"/""A+CO_2"dry ether"/(H^+/(H_2O))B+Mg(Br)OH`
Chapter: [10.01] Haloalkanes [10.02] Haloarenes
How ligands are classified? Explain with suitable examples.
Chapter: [0.09] Coordination Compounds
What is lanthanoid contraction?
Chapter: [8.02] F-block Elements
Explain, why lanthanum (Z = 57) forms La3+ ion, while cerium (Z = 58) forms Ce4+ ion?
Chapter: [8.02] F-block Elements
What is the action of phenyl hydrazine on propanone?
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids [12.01] Aldehydes and Ketones
What is the action of Zn – Hg / conc. HCl on propanone?
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids [12.01] Aldehydes and Ketones
What is the action of Sodium bisulphite on propanone?
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids [12.01] Aldehydes and Ketones
How is peptide linkage formed?
Chapter: [14.02] Proteins
How is nitroethane converted into ethylamine.
Chapter: [11.03] Ethers
How is nitroethane converted into N-ethylhydroxylamine
Chapter: [11.03] Ethers
How is nitroethane converted into acetic acid
Chapter: [11.03] Ethers
Write names and chemical formulae of monomers used in preparing Buna-N.
Chapter: [0.15] Polymers
How will you prepare ethanol, propan-2-ol and 2-methylpropan-2-ol from Grignard’s reagent?
Chapter: [11.01] Alcohols
Explain Optical activity
Chapter: [0.09] Coordination Compounds
Explain optical activity of lactic acid
Chapter: [0.09] Coordination Compounds
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