Advertisements
Advertisements
Question
Explain the following:
Silicon forms \[\ce{SiF^{2-}6}\] ion whereas corresponding fluoro compound of carbon is not known.
Solution
The bond dissociation energy decreases rapidly as the atomic size increases. Since the atomic size of carbon is much smaller (77 pm) as compared to that of silicon (118 pm), therefore, carbon-carbon bond dissociation energy is much higher (348 kJ mol–1) than that of silicon-silicon bond (297 kJ mol–1). Hence, because C – C bonds are much stronger as compared to Si-Si bonds, carbon has a much higher tendency for catenation than silicon.
APPEARS IN
RELATED QUESTIONS
Write suitable chemical equations to show the nature of the following oxide.
Tl2O3
Rationalise the given statement and give a chemical reaction:
Lead (IV) chloride is highly unstable towards heat.
Classify the following oxide as neutral, acidic, basic or amphoteric:
CO
Classify the following oxide as neutral, acidic, basic or amphoteric:
CO2
Write suitable chemical equations to show the nature of the following oxide.
Al2O3
The reason for small radius of Ga compared to Al is:
(i) poor screening effect of d and f orbitals.
(ii) increase in nuclear charge.
(iii) presence of higher orbitals.
(iv) higher atomic number.
Give reasons for the following:
CCl4 is immiscible in water, whereas SiCl4 is easily hydrolysed.
Carbon and silicon both belong to the group 14, but inspite of the stoichiometric similarity, the dioxides, (i.e., carbon dioxide and silicon dioxide), differ in their structures. Comment.
Explain the following:
Why does the element silicon, not form a graphite like structure whereas carbon does.
Stannous chloride solution when kept in the air turns milky due to the formation of ______.
