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Question
For the complex [Fe(CN)6]3–, write the hybridization type, magnetic character and spin nature of the complex. (At. number : Fe = 26).
Solution
Hybridisation:- d2sp3
Magnetic character:- Paramagnetic
Spin nature of complex:- Low-spin complex
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Assertion: \[\ce{[Fe(CN)6]^{3-}}\] ion shows magnetic moment corresponding to two unpaired electrons.
Reason: Because it has d2sp3 type hybridisation.