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प्रश्न
For the complex [Fe(CN)6]3–, write the hybridization type, magnetic character and spin nature of the complex. (At. number : Fe = 26).
उत्तर
Hybridisation:- d2sp3
Magnetic character:- Paramagnetic
Spin nature of complex:- Low-spin complex
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संबंधित प्रश्न
Write the hybridization and magnetic behaviour of the complex [Ni(CO)4].
(At.no. of Ni = 28)
Write the hybridization and shape of the following complexe : [CoF6]3–
(Atomic number : Co = 27, Ni = 28)
[Fe(H2O)6]3+ is strongly paramagnetic whereas [Fe(CN)6]3− is weakly paramagnetic. Explain.
Write down the IUPAC name of the following complex and indicate the oxidation state, electronic configuration and coordination number. Also, give the stereochemistry and magnetic moment of the complex:
K[Cr(H2O)2(C2O4)2].3H2O
Why is [NiCl4]2− paramagnetic while [Ni(CN)4]2− is diamagnetic? (Atomic number of Ni = 28)
Write the hybridization type and magnetic behaviour of the complex [Ni(CN)4]2−. (Atomic number of Ni = 28)
Which of the following options are correct for \[\ce{[Fe(CN)6]^{3-}}\] complex?
(i) d2sp3 hybridisation
(ii) sp3d2 hybridisation
(iii) paramagnetic
(iv) diamagnetic
Assertion: \[\ce{[Fe(CN)6]^{3-}}\] ion shows magnetic moment corresponding to two unpaired electrons.
Reason: Because it has d2sp3 type hybridisation.
Low oxidation state of metals in their complexes are common when ligands ______.
Explain [Fe(CN)6]3− is an inner orbital complex, whereas [FeF6]3− is an outer orbital complex.
[Atomic number: Fe = 26]
