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Karnataka Board PUCPUC Science 2nd PUC Class 12

How is O3 estimated quantitatively? - Chemistry

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Question

How is O3 estimated quantitatively?

Solution

Quantitatively, ozone can be estimated with the help of potassium iodide. When ozone is made to react with potassium iodide solution buffered with a borate buffer (pH 9.2), iodine is liberated. This liberated iodine can be titrated against a standard solution of sodium thiosulphate using starch as an indicator. The reactions involved in the process are given below.

`2I^(-)   + H_2O + O_3 ->  2OH^(-) + I_2 + O_2`

Iodide                Ozone                     Iodine

 

`I_2     +     2Na_2S_2O_3      ->         Na_2S_4O_6  + 2 Nal`

            Sodium thiosulphate          Sodium tetrathionate

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Chapter 7: The p-block Elements - Intext Questions [Page 187]

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NCERT Chemistry [English] Class 12
Chapter 7 The p-block Elements
Intext Questions | Q 19 | Page 187
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