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How is Phosphine Prepared Using the Following Reagent? Caustic Soda - Chemistry

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Question

How is phosphine prepared using the following reagent?

Caustic soda

Short Note

Solution

Preparation of Phosphine using Caustic soda (NaOH)
White phosphorus is heated with concentrated NaOH solution in an inert atmosphere of CO2. It is the laboratory method.

`P_4  +       3NaOH+3H_2O     ->  PH_3  +     3NaH_2PO_2`

White        Sodium hydroxide   Phosphine     Sodium
phosphorus                                                      hypophosphite

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2016-2017 (March)

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