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Karnataka Board PUCPUC Science Class 11

How would you explain the lower atomic radius of Ga as compared to Al? - Chemistry

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Question

How would you explain the lower atomic radius of Ga as compared to Al?

Answer in Brief

Solution

Atomic radius (in pm)
Aluminium 143
Gallium 135

Although Ga has one shell more than Al, its size is lesser than Al. This is because of the poor shielding effect of the 3d-electrons. The shielding effect of d-electrons is very poor and the effective nuclear charge experienced by the valence electrons in gallium is much more than it is in the case of Al.

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Group 13 Elements - The Boron Family
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Chapter 11: The p-Block Elements - EXERCISES [Page 332]

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NCERT Chemistry - Part 1 and 2 [English] Class 11
Chapter 11 The p-Block Elements
EXERCISES | Q 11.24 | Page 332

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