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Question
Match the property given in Column I with the element given in Column II.
| Column I (Property) | Column II (Element) | |
| (i) | Lanthanoid which shows +4 oxidation state |
(a) Pm |
| (ii) | Lanthanoid which can show +2 oxidation state |
(b) Ce |
| (iii) | Radioactive lanthanoid | (c) Lu |
| (iv) | Lanthanoid which has 4f7 electronic configuration in +3 oxidation state |
(d) Eu |
| (v) | Lanthanoid which has 4f14 electronic configuration in +3 oxidation state |
(e) Gd |
| (f) Dy |
Solution
| Column I (Property) | Column II (Element) | |
| (i) | Lanthanoid which shows +4 oxidation state |
(b) Ce |
| (ii) | Lanthanoid which can show +2 oxidation state |
(d) Eu |
| (iii) | Radioactive lanthanoid | (a) Pm |
| (iv) | Lanthanoid which has 4f7 electronic configuration in +3 oxidation state |
(e) Gd |
| (v) | Lanthanoid which has 4f14 electronic configuration in +3 oxidation state |
(c) Lu |
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RELATED QUESTIONS
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What is Lanthanoid contraction?
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Although +3 is the characteristic oxidation state for lanthanoids but cerium also shows +4 oxidation state because:
(i) it has variable ionisation enthalpy
(ii) it has a tendency to attain noble gas configuration
(iii) it has a tendency to attain f 0 configuration
(iv) it resembles Pb4+
Match the compounds/elements given in Column I with uses given in Column II.
| Column I (Compound/element) | Column II (Use) | |
| (i) | Lanthanoid oxide | (a) Production of iron alloy |
| (ii) | Lanthanoid | (b) Television screen |
| (iii) | Misch metal | (c) Petroleum cracking |
| (iv) | Magnesium based alloy is constituent of | (d) Lanthanoid metal + iron |
| (v) | Mixed oxides of lanthanoids are employed | (e) Bullets |
| (f) In X-ray screen |
On the basis of Lanthanoid contraction, explain the following:
Stability of the complexes of lanthanoids.
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