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Question
The stability of peroxide and superoxide of alkali metals increase as we go down the group. Explain giving reason.
Solution
As the size of metal ions increases, the stability of peroxides and superoxides increases. Peroxide and superoxide ions combine with a large size of alkali metals. Lithium forms monoxide, sodium forms peroxide and potassium, rubidium and caesium forms superoxide.
\[\ce{Li + O2 -> Li2O}\]
\[\ce{Na + O2 -> Na2O2}\]
\[\ce{K + O2 -> KO2}\]
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