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Question
What type of isomerism is shown by the complex [Co(NH3)5(SCN)]2+?
Solution
Linkage isomerism
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(i) \[\ce{[Co(NH3)5 (NO2)]^{2+}}\]
(ii) \[\ce{Co(H2O)5 CO]^{3+}}\]
(iii) \[\ce{[Cr(NH3)5 SCN]^{2+}}\]
(iv) \[\ce{Fe(en)2 Cl2]^+}\]
Match the complex species given in Column I with the possible isomerism given in Column II and assign the correct code:
| Column I (Complex species) | Column II (Isomerism) |
| A. \[\ce{[Co(NH3)4 Cl2]^+}\] | 1. optical |
| B. \[\ce{cis-[Co(en)2 Cl2]^+}\] | 2. ionisation |
| C. \[\ce{[Co(NH3)5 (NO2)]Cl2}\] | 3. coordination |
| D. \[\ce{[Co(NH3)6][Cr(CN)6]}\] | 4. geometrical |
| 5. linkage |
Which of the following compounds exhibits linkage isomerism?
Which isomer of C5H10 gives a single monochloro compound C5H9Cl in bright sunlight?
The complex [Co(NH3)5(NO2)]Cl2 is red in colour. Give IUPAC the name of its linkage isomer.
