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Which of the following orders are correct as per the properties mentioned against each? (i) AsX2OX3<SiOX2<PX2OX3<SOX2 Acid strength. (ii) AsHX3<PHX3<NHX3 Enthalpy of vapouris - Chemistry

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Question

Which of the following orders are correct as per the properties mentioned against each?

(i) \[\ce{As2O3 < SiO2 < P2O3 < SO2}\] Acid strength.
(ii) \[\ce{AsH3 < PH3 < NH3}\] Enthalpy of vapourisation.
(iii) \[\ce{S < O < Cl < F}\] More negative electron gain enthalpy.
(iv) \[\ce{H2O > H2S > H2Se > H2Te}\] Thermal stability.
Short Note

Solution

(i) \[\ce{As2O3 < SiO2 < P2O3 < SO2}\] Acid strength.
(iv) \[\ce{H2O > H2S > H2Se > H2Te}\] Thermal stability.

Explanation:

Acidic strength of oxides in a group decreases down the group and increases along a period from left to right.

Thermal stability of hydrides of group 16 decreases down the group.

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Chapter 7: The p-block Elements - Multiple Choice Questions (Type - I) [Page 95]

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NCERT Exemplar Chemistry [English] Class 12
Chapter 7 The p-block Elements
Multiple Choice Questions (Type - I) | Q 34 | Page 95

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