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Why do physisorption and chemisorption behave differently with rise in temperature? - Chemistry

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Question

Why do physisorption and chemisorption behave differently with rise in temperature?

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Solution

Physisorption involves weak van der Waals forces which weaken with rise in temperature. The chemisorption involves formation of chemical bond involving activation energy and like any other chemical reaction is favoured by rise in temperature.

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Chapter 5: Surface Chemistry - Exercises [Page 70]

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NCERT Exemplar Chemistry [English] Class 12
Chapter 5 Surface Chemistry
Exercises | Q III. 57. | Page 70

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