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Karnataka Board PUCPUC Science 2nd PUC Class 12

Why does nitrogen show catenation properties less than phosphorus? - Chemistry

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Question

Why does nitrogen show catenation properties less than phosphorus?

Solution

Catenation is much more common in phosphorous compounds than in nitrogen compounds. This is because of the relative weakness of the N−N single bond as compared to the P−P single bond. Since nitrogen atom is smaller, there is greater repulsion of electron density of two nitrogen atoms, thereby weakening the N−N single bond.

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Chapter 7: The p-block Elements - Exercises [Page 207]

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NCERT Chemistry [English] Class 12
Chapter 7 The p-block Elements
Exercises | Q 14 | Page 207
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