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Write Any ‘Four Points’ of Difference Between Fluorine and Other Halogens. - Chemistry

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Question

Write any ‘four points’ of difference between fluorine and other halogens.

Distinguish Between

Solution

  Fluorine Other halogens
Reactivity Fluorine is much more reactive due to its small atomic size, high nuclear 
charge and low F - F bond
dissociation energy
Other halogens are less reactive than fluorine.
Hydrogen bonding Hydrogen bonding is present in hydrides of fluorine. Hydrogen bonding is not present in hydrides of other halogens.
Oxidation state Due to the highest electronegativity and absence of the vacant d-orbitals in the valence shell, fluorine shows only -1 oxidation state in all its compounds.  Other halogens show -1 , + 1, + 3, +5 and + 7 oxidation states.
Polyhalide ions Due to absence of vacant d-orbitals in the valence shell, fluorine does not form any polyhalide ion.  Other halogens form polyhalide ions such as `"""I"_3^-, """Br"_3^-, """Cl"_3^-`.
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P - Block Group 17 Elements - Anomalous Behaviour of Fluorine
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2017-2018 (July) Set 1
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