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Question
Write down the IUPAC name of the following complex and indicate the oxidation state, electronic configuration and coordination number. Also, give the stereochemistry and magnetic moment of the complex:
K4[Mn(CN)6]
Solution
| IUPAC name of the hybrid compound | Oxidation state of the central metal | Coordination number | Shape | Central metal ion | Electronic configuration | The value of n and the magnetic moment | Stereochemistry |
| Potassium hexacyanomangana te(II) | (+1) × 4 + x + 6 × (−1) = 0 ∴ x = +2 |
6 | Octahedral | Mn2+ | 3d5, \[\ce{t^5_{2g}}\] | n = 1, `sqrt(1(1 + 2))` = 1.73 BM |
Optically inactive |
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