Advertisements
Online Mock Tests
Chapters
2: Solutions
3: Electrochemistry
4: Chemical Kinetics
5: Surface Chemistry
6: General Principles and Processes of Isolation of Elements
7: The p-block Elements
8: The d-block and f-block Elements
▶ 9: Coordinate Compounds
10: Haloalkanes and Haloarenes
11: Alcohols, Phenols and Ethers
12: Aldehydes, Ketones and Carboxylic Acids
13: Amines
14: Biomolecules
15: Polymers
16: Chemistry in Everyday Life
![NCERT solutions for Chemistry [English] Class 12 chapter 9 - Coordinate Compounds - Shaalaa.com](/images/9788174506481-chemistry-english-class-12_6:a55896f658974483bc7dc0613af00ce2.jpg "NCERT solutions for Chemistry [English] Class 12 chapter 9 - Coordinate Compounds")
Advertisements
Solutions for Chapter 9: Coordinate Compounds
Below listed, you can find solutions for Chapter 9 of CBSE, Karnataka Board PUC NCERT for Chemistry [English] Class 12.
NCERT solutions for Chemistry [English] Class 12 9 Coordinate Compounds Intext Questions [Pages 244 - 256]
Write the formula for the given coordination compound:
Tetraamminediaquacobalt (III) chloride
Write the formula for the given coordination compound:
Potassium tetracyanidonickelate (II)
Write the formula for the given coordination compound:
Tris(ethane−1, 2−diamine) chromium (III) chloride
Write the formula for the given coordination compound:
Amminebromidochloridonitrito-N-platinate (II)
Write the formula for the given coordination compound:
Dichloridobis(ethane−1, 2−diamine)platinum (IV) nitrate
Write the formula for the given coordination compound:
Iron (III) hexacyanoferrate (II)
Write the IUPAC name of the following coordination compound:
[Co(NH3)6]Cl3
Write the IUPAC name of the following coordination compound:
[Co(NH3)5Cl]Cl2
Write the IUPAC names of the following coordination compounds : K3[Fe(CN)6]
Write the IUPAC name of the following coordination compound:
K2[PdCl4]
Write the IUPAC name of the following coordination compound:
[Pt(NH3)2Cl(NH2CH3)]Cl
Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:
K[Cr(H2O)2(C2O4)2]
Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:
[Co(en)3]Cl3
Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:
[Co(NH3)5(NO2)](NO3)2
Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:
[Pt(NH3)(H2O)Cl2]
Give evidence that [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl are ionization isomers.
Explain on the basis of valence bond theory that [Ni(CN)4]2− ion with square planar structure is diamagnetic and the [NiCl4]2− ion with tetrahedral geometry is paramagnetic.
[NiCl4]2− is paramagnetic while [Ni(CO)4] is diamagnetic though both are tetrahedral. Why?
[Fe(H2O)6]3+ is strongly paramagnetic whereas [Fe(CN)6]3− is weakly paramagnetic. Explain.
Explain [Co(NH3)6]3+ is an inner orbital complex whereas [Ni(NH3)6]2+ is an outer orbital complex.
Predict the number of unpaired electrons in the square planar [Pt(CN)4]2− ion.
The hexaquo manganese (II) ion contains five unpaired electrons, while the hexacyanoion contains only one unpaired electron. Explain using Crystal Field Theory.
Calculate the overall complex dissociation equilibrium constant for the Cu(NH3)42+ ion, given that β4 for this complex is 2.1 × 1013.
NCERT solutions for Chemistry [English] Class 12 9 Coordinate Compounds Exercises [Pages 258 - 260]
Explain the bonding in coordination compounds in terms of Werner’s postulates.
FeSO4 solution mixed with (NH4)2SO4 solution in 1 : 1 molar ratio gives the test of Fe2+ ion but CuSO4 solution mixed with aqueous ammonia in 1 : 4 molar ratio does not give the test of Cu2+ ion. Explain why?
Explain the following, giving two examples:
Coordination entity
What is meant by unidentate ligand?
Give two examples of unidentate ligand.
What is meant by didentate ligand?
Give two examples of didentate ligand.
What is meant by ambidentate ligand?
Give two examples of ambidentate ligand.
Specify the oxidation number of the metal in the following coordination entity:
[Co(H2O)(CN)(en)2]2+
Specify the oxidation number of the metal in the following coordination entity:
[CoBr2(en)2]+
Specify the oxidation number of the metal in the following coordination entity:
[PtCl4]2−
Specify the oxidation number of the metal in the following coordination entity:
K3[Fe(CN)6]
Specify the oxidation number of the metal in the following coordination entity:
[Cr(NH3)3Cl3]
Using IUPAC norms, write the formula for the following:
Tetrahydroxidozincate(II)
Using IUPAC norms, write the formula for the following:
Potassium tetrachloridopalladate(II)
Using IUPAC norms, write the formula for the following:
Diamminedichloridoplatinum(II)
Write the formula for the following complex:
Pentaamminenitrito-O-Cobalt (III)
Using IUPAC norms, write the formula for the following:
Hexaamminecobalt(III) sulphate
Using IUPAC norms, write the formula for the following:
Potassium tri(oxalato)chromate(III)
Using IUPAC norms, write the formula for the following:
Tetrabromidocuprate(II)
Using IUPAC norms write the systematic name of the following:
[Co(NH3)6]Cl3
Using IUPAC norms write the systematic name of the following:
[Pt(NH3)2Cl(NH2CH3)]Cl
Using IUPAC norms, write the systematic name of the following:
[Ti(H2O)6]3+
Using IUPAC norms, write the systematic name of the following:
[Co(NH3)4Cl(NO2)]Cl
Using IUPAC norms, write the systematic name of the following:
[Mn(H2O)6]2+
Using IUPAC norms, write the systematic name of the following:
[NiCl4]2−
Using IUPAC norms, write the systematic name of the following:
[Ni(NH3)6]Cl2
Using IUPAC norms, write the systematic name of the following:
[Co(en)3]3+
Using IUPAC norms, write the systematic name of the following:
[Ni(CO)4]
List various types of isomerism possible for coordination compounds, giving an example of each.
How many geometrical isomers are possible in the following coordination entity?
[Cr(C2O4)3]3−
How many geometrical isomers are possible in the following coordination entity?
[Co(NH3)3Cl3]
Draw the structure of optical isomers of [Cr(C2O4)3]3−.
Draw the structure of optical isomers of [PtCl2(en)2]2+.
Draw the structure of optical isomers of [Cr(NH3)2Cl2(en)]+.
Draw all the isomers (geometrical and optical) of [CoCl2(en)2]+.
Draw all the isomers (geometrical and optical) of [Co(NH3)Cl(en)2]2+.
Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.
Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?
Aqueous copper sulphate solution (blue in colour) gives a green precipitate with aqueous potassium fluoride. Explain this experimental result.
What is the coordination entity formed when excess of aqueous KCN is added to an aqueous solution of copper sulphate? Why is it that no precipitate of copper sulphide is obtained when H2S(g) is passed through this solution?
Discuss the nature of bonding in the following coordination entity on the basis of valence bond theory:
[Fe(CN)6]4−
Discuss the nature of bonding in the following coordination entity on the basis of valence bond theory:
[FeF6]3−
Discuss the nature of bonding in the following coordination entity on the basis of valence bond theory:
[Co(C2O4)3]3−
Discuss the nature of bonding in the following coordination entity on the basis of valence bond theory:
[CoF6]3−
Draw figure to show the splitting of d orbitals in an octahedral crystal field.
What is spectrochemical series? Explain the difference between a weak field ligand and a strong field ligand.
What is crystal field splitting energy?
How does the magnitude of Δ0 decide the actual configuration of d orbitals in a coordination entity?
[Cr(NH3)6]3+ is paramagnetic while [Ni(CN)4]2− is diamagnetic. Explain why?
A solution of [Ni(H2O)6]2+ is green but a solution of [Ni(CN)4]2− is colourless. Explain.
[Fe(CN)6]4− and [Fe(H2O)6]2+ are of different colours in dilute solutions. Why?
Discuss the nature of bonding in metal carbonyls.
Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
K3[Co(C2O4)3]
Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
cis-[CrCl2(en)2]Cl
Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
(NH4)2[CoF4]
Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
[Mn(H2O)6]SO4
Write down the IUPAC name of the following complex and indicate the oxidation state, electronic configuration and coordination number. Also, give the stereochemistry and magnetic moment of the complex:
K[Cr(H2O)2(C2O4)2].3H2O
Write down the IUPAC name of the following complex and indicate the oxidation state, electronic configuration and coordination number. Also, give the stereochemistry and magnetic moment of the complex:
[Co(NH3)5Cl]Cl2
Write down the IUPAC name of the following complex and indicate the oxidation state, electronic configuration and coordination number. Also, give the stereochemistry and magnetic moment of the complex:
[CrCl3(py)3]
Write down the IUPAC name of the following complex and indicate the oxidation state, electronic configuration and coordination number. Also, give the stereochemistry and magnetic moment of the complex:
Cs[FeCl4]
Write down the IUPAC name of the following complex and indicate the oxidation state, electronic configuration and coordination number. Also, give the stereochemistry and magnetic moment of the complex:
K4[Mn(CN)6]
What is meant by stability of a coordination compound in solution? State the factors which govern stability of complexes.
What is meant by the chelate effect?
Give an example of chelate effect.
Discuss briefly, giving an example of the role of coordination compounds in biological systems.
Discuss briefly, giving an example of the role of coordination compounds in medicinal chemistry.
Discuss briefly, giving an example of the role of coordination compounds in analytical chemistry.
Discuss briefly, giving an example of the role of coordination compounds in extraction/metallurgy of metals.
How many ions are produced from the complex Co(NH3)6Cl2 in solution?
6
4
3
2
Amongst the following ions, which one has the highest magnetic moment value?
[Cr(H2O)6]3+
[Fe(H2O)6]2+
[Zn(H2O)6]2+
The oxidation number of cobalt in K[Co(CO)4] is
(i) +1
(ii) +3
(iii) −1
(iv) −3
Amongst the following, the most stable complex is:
[Fe(H2O)6]3+
[Fe(NH3)6]3+
[Fe(C2O4)3]3−
[FeCl6]3−
What will be the correct order for the wavelengths of absorption in the visible region for the following?
[Ni(NO2)6]4−, [Ni(NH3)6]2+, [Ni(H2O)6]2+
Solutions for 9: Coordinate Compounds
NCERT solutions for Chemistry [English] Class 12 chapter 9 - Coordinate Compounds
Shaalaa.com has the CBSE, Karnataka Board PUC Mathematics Chemistry [English] Class 12 CBSE, Karnataka Board PUC solutions in a manner that help students grasp basic concepts better and faster. The detailed, step-by-step solutions will help you understand the concepts better and clarify any confusion. NCERT solutions for Mathematics Chemistry [English] Class 12 CBSE, Karnataka Board PUC 9 (Coordinate Compounds) include all questions with answers and detailed explanations. This will clear students' doubts about questions and improve their application skills while preparing for board exams.
Further, we at Shaalaa.com provide such solutions so students can prepare for written exams. NCERT textbook solutions can be a core help for self-study and provide excellent self-help guidance for students.
Concepts covered in Chemistry [English] Class 12 chapter 9 Coordinate Compounds are Introduction of Coordination Compounds, Definitions of Some Important Terms Pertaining to Coordination Compounds, Nomenclature of Coordination Compounds - Naming of Mononuclear Coordination Compounds, Bonding in Coordination Compounds - Introduction, Werner’s Theory of Coordination Compounds, Valence Bond Theory (VBT), Stereoisomerism, Nomenclature of Coordination Compounds - Formulas of Mononuclear Coordination Entities, Structural Isomerism, Isomerism in Coordination Compounds, Coordination Compounds Numerical, Types of Ligands, Magnetic Properties of Coordination Compounds, Crystal Field Theory (CFT), Colour in Coordination Compounds, Bonding in Metal Carbonyls, Stability of Coordination Compounds, Importance and Applications of Coordination Compounds, Introduction of Coordination Compounds, Definitions of Some Important Terms Pertaining to Coordination Compounds, Nomenclature of Coordination Compounds - Naming of Mononuclear Coordination Compounds, Bonding in Coordination Compounds - Introduction, Werner’s Theory of Coordination Compounds, Valence Bond Theory (VBT), Stereoisomerism, Nomenclature of Coordination Compounds - Formulas of Mononuclear Coordination Entities, Structural Isomerism, Isomerism in Coordination Compounds, Coordination Compounds Numerical, Types of Ligands, Magnetic Properties of Coordination Compounds, Crystal Field Theory (CFT), Colour in Coordination Compounds, Bonding in Metal Carbonyls, Stability of Coordination Compounds, Importance and Applications of Coordination Compounds.
Using NCERT Chemistry [English] Class 12 solutions Coordinate Compounds exercise by students is an easy way to prepare for the exams, as they involve solutions arranged chapter-wise and also page-wise. The questions involved in NCERT Solutions are essential questions that can be asked in the final exam. Maximum CBSE, Karnataka Board PUC Chemistry [English] Class 12 students prefer NCERT Textbook Solutions to score more in exams.
Get the free view of Chapter 9, Coordinate Compounds Chemistry [English] Class 12 additional questions for Mathematics Chemistry [English] Class 12 CBSE, Karnataka Board PUC, and you can use Shaalaa.com to keep it handy for your exam preparation.
