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Question
How many geometrical isomers are possible in the following coordination entity?
[Co(NH3)3Cl3]
Solution
Two geometrical isomers are possible.
\[\begin{array}{cc} \phantom{..}\ce{Cl}\phantom{....}\ce{NH3}\phantom{.}\ce{NH3}\\ \backslash\phantom{...}|\phantom{...}/\\ \phantom{.}\ce{Co}\\ /\phantom{...}|\phantom{...}\backslash\\ \ce{\underset{fac}{\phantom{..}Cl\phantom{...}Cl\phantom{...}NH3}} \end{array}\] |
\[\begin{array}{cc} \ce{NH3}\phantom{...}\ce{NH3}\phantom{.}\ce{Cl}\phantom{..}\\ \backslash\phantom{...}|\phantom{...}/\\ \phantom{.}\ce{Co}\\ /\phantom{...}|\phantom{...}\backslash\\ \ce{\underset{mer}{Cl\phantom{...}NH3\phantom{.}Cl}} \end{array}\] |
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