Advertisements
Advertisements
Question
Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:
[Co(en)3]Cl3
Solution 1
Two optical isomers for [Co(en)3]Cl3 exits.
Solution 2
It may have two optical isomers.
APPEARS IN
RELATED QUESTIONS
Explain cationic complexes and anionic complexes of co-ordination compounds.
When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3moles of AgCl are precipitated per mole of the compound. Write
(i) Structural formula of the complex
Draw one of the geometrical isomers of the complex [Pt (en)2Cl2] +2 which is optically inactive
Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]2+ which is optically active.
What type of isomerism is exhibited by the complex [Co(en)3]3+?
(en = ethane-1,2-diamine)
How many geometrical isomers are possible in the following coordination entity?
[Cr(C2O4)3]3−
Draw the structure of optical isomers of [Cr(C2O4)3]3−.
Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.
What type of isomers are `[Co(NH_3)_5Br]SO_4`and `[Co(NH_3)_5SO_4]Br`?. Give a chemical test to distinguish between them.
Name the type of isomerism exhibited by the following pairs of compound:
(1) (C2H5)2NH and CH3-NH-C3H7
(2) 1 – butanol and 2 methyl-1 -propanol.
Name the type of isomerism shown by the following pair of compounds:
[CoCl(H2O)(NH3)4]Cl2 and [CoCl2(NH3)4]Cl.H2O
Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.
Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.
Indicate the types of isomerism exhibited by the following complexes and draw the structure for isomers:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Assertion: Addition of bromine water to 1-butene gives two optical isomers.
Reason: The product formed contains two asymmetric carbon atoms.
Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer:
[Pt(NH3)(H2O)Cl2]
Indicate the types of isomerism exhibited by the following complex and draw the structure for these isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
\[\ce{[Pt(NH3 )(H2O)Cl2]}\]
